The electrochemical characteristics of VSe2 in lithium cells
DOI: 10.1016/0025-5408(78)90108-3
关键词: Inorganic chemistry 、 Electrochemistry 、 Alkali metal 、 Electromotive force 、 Diselenide 、 Electrochemical cell 、 Chemistry 、 Titanium disulfide 、 Lithium vanadium phosphate battery 、 Vanadium
摘要: Vanadium diselenide has been found to react in a reversible manner with lithium in electrochemical cells. The rate of reaction was very rapid, comparable with that of titanium disulfide. The partial molar free energy of reaction was found to be almost independent of composition for x≤ 1 in Li x VSe 2. A second lithium was incorporated into the lattice but only at cell emf's of around 1.3 volts, 0.7 volts lower than for the first lithium.
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