Electron beam dissociation of CO and CO2 on ZnS thin films

作者: Y. Darici , P. H. Holloway , J. Sebastian , T. Trottier , S. Jones

DOI: 10.1116/1.581688

关键词:

摘要: The effects of electron bombardment in 10−6 Torr CO or CO2 upon the surface composition ZnS thin films was determined with Auger spectroscopy. stable 1×10−9 residual vacuum for and exposures without bombardment. With both present, C deposited S decreased, but no O accumulated on surface. This interpreted as an beam stimulated reaction which dissociated by reformed leaving For CO2, were increased while reduced. a involving dissociation reformation COx data suggest that did not occur when sample temperature from 30 °C to 150–200 °C. At 300 °C, diffused substrate consequences these reactions cathodolumin...

参考文章(30)
F.-L. Zhang, S. Yang, C. Stoffers, J. Penczek, P. N. Yocom, D. Zaremba, B. K. Wagner, C. J. Summers, Low voltage cathodoluminescence properties of blue emitting SrGa2S4:Ce3+ and ZnS:Ag,Cl phosphors Applied Physics Letters. ,vol. 72, pp. 2226- 2228 ,(1998) , 10.1063/1.121266
W. Hanle, K. H. Rau, Lichtausbeuten und Zerstörung von Leuchtstoffen bei Elektronen- und Ionenstoß European Physical Journal A. ,vol. 133, pp. 297- 308 ,(1952) , 10.1007/BF01948706
J. Sebastian, S. Jones, T. Trottier, H. Swart, P. Holloway, Electron-stimulated surface reactions between residual vacuum gas and ZnS field-emission-display phosphors Journal of The Society for Information Display. ,vol. 3, pp. 147- 149 ,(1995) , 10.1889/1.1984956
C. A. Spindt, A Thin‐Film Field‐Emission Cathode Journal of Applied Physics. ,vol. 39, pp. 3504- 3505 ,(1968) , 10.1063/1.1656810
F. Ohuchi, M. Ogino, P. H. Holloway, C. G. Pantano, Electron beam effects during analysis of glass thin films with auger electron spectroscopy Surface and Interface Analysis. ,vol. 2, pp. 85- 90 ,(1980) , 10.1002/SIA.740020303
C. R. Ronda, H. Bechtel, U. Kynast, T. Welker, The degradation behavior of LaOBr:Tb under cathode‐ray excitation Journal of Applied Physics. ,vol. 75, pp. 4636- 4641 ,(1994) , 10.1063/1.355913
F. Ohuchi, P. H. Holloway, General model of sodium desorption and diffusion during electron bombardment of glass Journal of Vacuum Science and Technology. ,vol. 20, pp. 863- 867 ,(1982) , 10.1116/1.571367
P. R. Schwoebel, Surface-science aspects of vacuum microelectronics Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures. ,vol. 13, pp. 1391- 1410 ,(1995) , 10.1116/1.588219
J. M. Martinez, J. B. Hudson, The Adsorption and Decomposition of CO on Pt(111) Journal of Vacuum Science and Technology. ,vol. 10, pp. 35- 38 ,(1973) , 10.1116/1.1318038
H. C. Swart, J. S. Sebastian, T. A. Trottier, S. L. Jones, P. H. Holloway, Degradation of zinc sulfide phosphors under electron bombardment Journal of Vacuum Science and Technology. ,vol. 14, pp. 1697- 1703 ,(1996) , 10.1116/1.580322