The emission spectroscopy of the e1Π–a1Δ system of VN molecule

作者: Qunchao Fan , Shi Hu , Weiguo Sun , Qi Wang

DOI: 10.1016/J.SAA.2013.05.040

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摘要: Abstract Vanadium nitride is an important metallurgical additive and a good electrode material molecule. It necessary to understand its intrinsic microstructure for better applications. Four groups of known experimental transition data low-lying rotational quantum states the analytical formula developed recently by Sun group are used study Ree, Pee, Rff Pff-branch emission spectra (0, 0) band e 1 Π - Δ system VN molecule respectively. The results not only reproduce all spectral lines accurately, but also generate valid unknown up J = 80 that may be available experimentally.

参考文章(16)
R.S. Ram, P.F. Bernath, S.P. Davis, Emission Spectroscopy of the d1Σ+–b1Σ+, d1Σ+–X3Δ1, and e1Π–a1Δ Systems of VN Journal of Molecular Spectroscopy. ,vol. 210, pp. 110- 118 ,(2001) , 10.1006/JMSP.2001.8436
Weiguo Sun, Qunchao Fan, Huidong Li, Hao Feng, Studies on the P-branch spectral lines of rovibrational transitions of diatomic system. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 79, pp. 35- 38 ,(2011) , 10.1016/J.SAA.2011.01.013
James F. Harrison, Electronic Structure of the Transition Metal Nitrides TiN, VN, and CrN The Journal of Physical Chemistry. ,vol. 100, pp. 3513- 3519 ,(1996) , 10.1021/JP952648H
B. R. Zhao, L. Chen, H. L. Luo, M. D. Jack, D. P. Mullin, Superconducting and normal-state properties of vanadium nitride Physical Review B. ,vol. 29, pp. 6198- 6202 ,(1984) , 10.1103/PHYSREVB.29.6198
P.A.P. Nascente, R.M. Muñoz Riofano, L.C. Casteletti, Study of the wear behavior of ion nitrided steels with different vanadium contents Surface & Coatings Technology. ,vol. 200, pp. 6101- 6110 ,(2006) , 10.1016/J.SURFCOAT.2005.09.026
M.A. Flory, L.M. Ziurys, Submillimeter-wave spectroscopy of VN (X3Δr) and VO (X4Σ−): A study of the hyperfine interactions Journal of Molecular Spectroscopy. ,vol. 247, pp. 76- 84 ,(2008) , 10.1016/J.JMS.2007.09.007
Xiaoping Zhou, Hongyu Chen, Dong Shu, Chun He, Junmin Nan, Study on the electrochemical behavior of vanadium nitride as a promising supercapacitor material Journal of Physics and Chemistry of Solids. ,vol. 70, pp. 495- 500 ,(2009) , 10.1016/J.JPCS.2008.12.004
R.S Ram, P.F Bernath, S.P Davis, NoteFourier Transform Emission Spectroscopy of the f1Φ–a1Δ System of VN Journal of Molecular Spectroscopy. ,vol. 215, pp. 163- 164 ,(2002) , 10.1006/JMSP.2002.8617