Chemistry of 2‐oxazolines: A crossing of cationic ring‐opening polymerization and enzymatic ring‐opening polyaddition
作者： Akira Makino , Shiro Kobayashi
DOI: 10.1002/POLA.23906
关键词:
摘要: Chemistry of 2-oxazolines is involved in the polymer synthesis fields cationic ring-opening polymerization (CROP) and enzymatic polyaddition (EROPA), although both polymerizations look like a quite different class reaction. The key for to proceed combination catalyst (initiator) design monomers. This article describes recent developments via these two kinds afford various functional polymers having completely structures, poly(N-acylethylenimine)s CROP 2-amino-2-deoxy sugar unit-containing oligo polysaccharides EROPA, respectively. From viewpoint reaction mode, an acid-catalyzed (ROPA) considered be crossing where EROPA meet. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Chem 48: 1251–1270,
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