Electron affinities of the XYH3 systems (X, Y=C, Si)
作者： Josef Kalcher , Alexander F. Sax
DOI: 10.1016/0009-2614(88)80403-2
关键词:
摘要: Abstract Electron affinities (EA) of the title compounds are investigated. The CCH 3 − anion turns out to be unstable, whereas positive EAs predicted for CSiH , SiCH and SiSiH . For as well there should exist at least one stable excited state. Pronounced influence YH substituent on adiabatic electron thus stabilities anions is observed.
elsevier.com
sci-hub.se 参考文章(32)
Thomas P. Beebe, John T. Yates, Infrared spectroscopic investigation of the ethylene chemisorption reaction on supported metallic catalyst surfaces: Ethylidyne formation on platinum, rhodium, palladium, and ruthenium supported on alumina The Journal of Physical Chemistry. ,vol. 91, pp. 254- 257 ,(1987) , 10.1021/J100286A003
Josef Kalcher, Ab initio and pseudopotential investigations on the SiHn (n = 1–3) radicals and their anions principles and practice of constraint programming. ,vol. 118, pp. 273- 284 ,(1987) , 10.1016/0301-0104(87)87043-X
Stephen W. Froelicher, Ben S. Freiser, Robert R. Squires, C3H5- isomers. Experimental and theoretical studies of tautomeric propenyl ions and the cyclopropyl anion in the gas phase Journal of the American Chemical Society. ,vol. 108, pp. 2853- 2862 ,(1986) , 10.1021/JA00271A012
Nancy J. Jensen, Kenneth B. Tomer, Michael L. Gross, Gas-phase ion decomposition occurring remote to a charge site Journal of the American Chemical Society. ,vol. 107, pp. 1863- 1868 ,(1985) , 10.1021/JA00293A010
G. Leroy, C. Wilante, D. Peeters, M.M. Uyewa, A theoretical investigation of the properties of carbocations and carbanions Journal of Molecular Structure-theochem. ,vol. 124, pp. 107- 131 ,(1985) , 10.1016/0166-1280(85)87024-X
JA Horsley, J Stöhr, RJ Koestner, None, Structure and bonding of chemisorbed ethylene and ethylidyne on Pt(111) from near edge x-ray absorption fine structure spectroscopy and multiple scattering calculations Journal of Chemical Physics. ,vol. 83, pp. 3146- 3153 ,(1985) , 10.1063/1.449220
Hans‐Joachim Werner, Ernst‐Albrecht Reinsch, The self‐consistent electron pairs method for multiconfiguration reference state functions Journal of Chemical Physics. ,vol. 76, pp. 3144- 3156 ,(1982) , 10.1063/1.443357
Josef Kalcher, On the stabilities of the singly and doubly negative atomic ions of Si, P, S, and Cl principles and practice of constraint programming. ,vol. 115, pp. 33- 42 ,(1987) , 10.1016/0301-0104(87)80176-3
Po Kang Wang, Charles P. Slichter, John H. Sinfelt, Structures and reactions of ethylene (C2H4) adsorbed on small platinum clusters The Journal of Physical Chemistry. ,vol. 89, pp. 3606- 3609 ,(1985) , 10.1021/J100263A007
Kelley R. Lane, Robert E. Lee, Larry Sallans, Robert R. Squires, Formation and reactivity of the iron carboxylic acid anion Fe(CO)4COOH- in the gas phase. Implications for the iron pentacarbonyl-catalyzed water-gas shift reaction Journal of the American Chemical Society. ,vol. 106, pp. 5767- 5772 ,(1984) , 10.1021/JA00332A001