A theoretical investigation of the properties of carbocations and carbanions
作者： G. Leroy , C. Wilante , D. Peeters , M.M. Uyewa
DOI: 10.1016/0166-1280(85)87024-X
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摘要: Abstract We show in this paper that the enthalpy changes and, eventually, rate constants of any physical or chemical process involving carbocations and (or) carbanions can be rationalized terms stabilization energies these species. The ionization heterolytic bond dissociation processes also ionic additions to alkenes have been particularly studied Work. In context, a series interesting relations between thermodynamic kinetic parameters derived.
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