Effect of the Helical Tether of a Resin-Supported Peptide Catalyst for Friedel–Crafts-Type Alkylation in Water
作者： Kengo Akagawa , Rieko Suzuki , Kazuaki Kudo
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摘要: A detailed investigation of the helical part resin-supported peptide catalyst possessing a turn motif and unit was conducted to clarify structure-activity relationship. The with an α- or 310-helical tether effective for enantioselective Friedel–Crafts-type alkylation in water. From spectral analysis optimum sequence, it demonstrated that moiety played role stabilizing terminal structure.
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