Peptide-catalyzed kinetic resolution of planar-chiral metallocenes
作者： Midori Akiyama , Kengo Akagawa , Hidetake Seino , Kazuaki Kudo
DOI: 10.1039/C4CC03266G
关键词:
摘要: Kinetic resolution of racemic planar-chiral metallocenes was performed through the conjugate addition a nucleophile to enal part substrates. While no enantiomeric discrimination found with low-molecular-weight organocatalysts, properly designed resin-supported peptide catalyzed reaction in highly selective manner.
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