Synthesis and properties of zirconium-doped RbTiOPO4 single crystals
作者： E. I. Agapova , V. I. Voronkova , E. P. Kharitonova , I. N. Leont’eva , S. Yu. Stefanovich
DOI: 10.1134/S1063774508020181
关键词:
摘要: Single crystals of the solid solutions RbTi1 − x Zr OPO4 (0.015 < x 0.034) were grown and their physical properties studied. In presence zirconium in with maximum content = 0.034, ferroelectric phase transition high-temperature from orthorhombic to cubic are shifted lower temperatures by 100 50°C, respectively. temperature range 700°C room temperature, conductivity doped decreases compared that undoped crystals. It is particular interest intensity second-harmonic generation substantially higher than RbTiOPO4.
springer.com
osti.gov
sci-hub.se 参考文章(11)
Valery I. Chani, Kiyoshi Shimamura, Tsuguo Fukuda, Crystallization of V5+- and Zr4+-Substituted KTiOPO4 Crystals from Flux Japanese Journal of Applied Physics. ,vol. 34, pp. 1615- 1618 ,(1995) , 10.1143/JJAP.34.1615
F. C. Zumsteg, J. D. Bierlein, T. E. Gier, KxRb1−xTiOPO4: A new nonlinear optical material Journal of Applied Physics. ,vol. 47, pp. 4980- 4985 ,(1976) , 10.1063/1.322459
Mark L. F. Phillips, William T. A. Harrison, Galen D. Stucky, Eugene M. McCarron, Joseph C. Calabrese, Thurman E. Gier, Effects of substitution chemistry in the potassium titanyl phosphate (KTiOPO4) structure field Chemistry of Materials. ,vol. 4, pp. 222- 233 ,(1992) , 10.1021/CM00019A041
V. K. Yanovskii, V. I. Voronkova, Ferroelectric Phase Transitions and Properties of Crystals of the KTiOPO4 Family Physica Status Solidi (a). ,vol. 93, pp. 665- 668 ,(1986) , 10.1002/PSSA.2210930232
John D. Bierlein, Herman Vanherzeele, A. A. Ballman, Linear and nonlinear optical properties of flux‐grown KTiOAsO4 Applied Physics Letters. ,vol. 54, pp. 783- 785 ,(1989) , 10.1063/1.101552
V. I. Voronkova, V. K. Yanovskii, I. N. Leont?eva, E. I. Agapova, E. P. Kharitonova, S. Yu. Stefanovich, S. A. Zver?kov, Growth and properties of Zr-doped KTiOPO4 crystals Inorganic Materials. ,vol. 40, pp. 1321- 1323 ,(2004) , 10.1007/S10789-005-0018-Z
P.A. Thomas, B.E. Watts, An Nb-doped analogue of KTiOPO4; Structural and nonlinear optical properties Solid State Communications. ,vol. 73, pp. 97- 100 ,(1990) , 10.1016/0038-1098(90)91025-C
V Nikolov, I Koseva, P Peshev, X Solans, R Solé, X Ruiz, Jna Gavaldà, J Massons, M Aguiló, F Dı́az, None, Flux growth of KTiOPO4 single crystals doped with Me4+ ions Materials Research Bulletin. ,vol. 34, pp. 1403- 1409 ,(1999) , 10.1016/S0025-5408(99)00137-3
Galen D. Stucky, Mark L. F. Phillips, Thurman E. Gier, The potassium titanyl phosphate structure field: a model for new nonlinear optical materials Chemistry of Materials. ,vol. 1, pp. 492- 509 ,(1989) , 10.1021/CM00005A008
Zhang Kecong, Wang Ximin, Structure sensitive properties of KTP-type crystals Chinese Science Bulletin. ,vol. 46, pp. 2028- 2036 ,(2001) , 10.1007/BF02901124