Synthesis and properties of epoxy resins containing bis(3-hydroxyphenyl) phenyl phosphate
作者： Chun-Shan Wang , Jeng-Yueh Shieh
DOI: 10.1016/S0014-3057(99)00091-9
关键词:
摘要: A reactive phosphorus-containing diol compound, bis(3-hydroxyphenyl) phenyl phosphate (BHPP), was synthesized. The compound (BHPP) used as a flame-retardant for diglycidyl ether of bisphenol-A (DGEBA). Thermal stability and the weight loss behavior cured polymers were studied by thermogravimetric analysis. phosphorous-containing epoxy resin showed lower temperature higher char yield than that DGEBA. high yields limiting oxygen index values well excellent UL-94 vertical burn test results BHPP/DGEBA indicated flame retardancy resins. resulting exhibited better thermal regular bromine containing retardant in encapsulation application. UL 94-VO rating could be achieved with phosphorus content low 1.5% (comparable to 10%) resin, no fume toxic gas emission observed.
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sci-hub.se 参考文章(21)
Handbook of Composites Chapman & Hall. ,(1998) , 10.1007/978-1-4615-6389-1
Pedro-Alberto Martínez, Virginia Cádiz, Ana Mantecón, Angels Serra, Synthesis, characterization, and thermal behaviour of new epoxy polyesterimides Angewandte Makromolekulare Chemie. ,vol. 133, pp. 97- 109 ,(1985) , 10.1002/APMC.1985.051330108
Sukumar Maiti, Susanta Banerjee, Sunanda K. Palit, Phosphorus-containing polymers Progress in Polymer Science. ,vol. 18, pp. 227- 261 ,(1993) , 10.1016/0079-6700(93)90026-9
H. Sivriev, S. Georgiev, G. Borissov, Phosphorus-containing polyurethanes, prepared by N-modification European Polymer Journal. ,vol. 26, pp. 73- 76 ,(1990) , 10.1016/0014-3057(90)90100-I
John A. Mikroyannidis, Demetrius A. Kourtides, Curing of epoxy resins with 1-/di(2-chloroethoxyphosphinyl)methyl/-2,4- and -2,6-diaminobenzene Journal of Applied Polymer Science. ,vol. 29, pp. 197- 209 ,(1984) , 10.1002/APP.1984.070290118
D.W van Krevelen, Some basic aspects of flame resistance of polymeric materials Polymer. ,vol. 16, pp. 615- 620 ,(1975) , 10.1016/0032-3861(75)90157-3
M. Sato, M. Yokoyama, Preparation of phosphorus-containing polymers—XV. Preparation of phosphorus-containing polyamide-imides from N,N′-bis(4-carboxyphthalimido)-3,3′-diphenylalkylphosphine oxide and aromatic diacetamides European Polymer Journal. ,vol. 15, pp. 75- 79 ,(1979) , 10.1016/0014-3057(79)90252-0
Wei-Kuo Chin, Min-Da Shau, Wei-Chun Tsai, Synthesis, structure, and thermal properties of epoxy‐imide resin cured by phosphorylated diamine Journal of Polymer Science Part A. ,vol. 33, pp. 373- 379 ,(1995) , 10.1002/POLA.1995.080330304
Chun-Shan Wang, Jeng-Yueh Shieh, Synthesis and properties of epoxy resins containing 2-(6-oxid-6H-dibenz(c,e)(1,2) oxaphosphorin-6-yl) 1,4-benzenediol (II) Polymer. ,vol. 39, pp. 5819- 5826 ,(1998) , 10.1016/S0032-3861(97)10292-0
Ying-Ling Liu, Ging-Ho Hsiue, Yie-Shun Chiu, Ru-Jong Jeng, Chong Ma, Synthesis and flame‐retardant properties of phosphorus‐containing polymers based on poly(4‐hydroxystyrene) Journal of Applied Polymer Science. ,vol. 59, pp. 1619- 1625 ,(1996) , 10.1002/(SICI)1097-4628(19960307)59:10<1619::AID-APP14>3.0.CO;2-R