Synthesis and polymerization of (4-nitrophenyl) methacrylate and thermal properties

作者: Roghayeh Soltanmoradi , Mohammad Hossein Nasirtabrizi

DOI: 10.17776/CSJ.14771

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摘要: Abstract. The monomer 4-nitrophenyl methacrylate (NPMA) is synthesized by reaction 4-nitrophenol and methacryloyl choloride. After characterization of this monomer, IR 1 HNMR spectroscopic technique. homo-and copolymers were with methyl (MMA) styrene (ST) free radical polymerization using dimethyl formamide (DMF) as a solvent azobis isobutyronitrile (AIBN) an initiator at 70±1˚C. resulting homopolymer characterized sepectroscopy. solubility the polymers was tested in various polar non-polar solvents. thermal behaviour present compounds has been determined means differential analysis (DTA) thermogravimetry (TGA) techniques. glass transition temperature poly(NPMA) increase NPMA content. Thus stability

参考文章(9)
Jian Li Hua, Jacky Wing Yip Lam, Hongchen Dong, Lijun Wu, Kam Sing Wong, Ben Zhong Tang, Synthesis, light emission, and photo-cross-linking of luminescent polyacetylenes containing acrylic pendant groups Polymer. ,vol. 47, pp. 18- 22 ,(2006) , 10.1016/J.POLYMER.2005.11.046
P. S. Vijayanand, A. Penlidis, S. Radhakrishnan, S. Nanjundan, COPOLYMERS OF 3,5-DIMETHYLPHENYL METHACRYLATE AND METHYLMETHACRYLATE: SYNTHESIS, CHARACTERIZATION, AND DETERMINATION OF REACTIVITY RATIOS Journal of Macromolecular Science, Part A. ,vol. 39, pp. 591- 608 ,(2002) , 10.1081/MA-120004249
C. S. Jone Selvamalar, P. S. Vijayanand, A. Penlidis, S. Nanjundan, Homopolymer and copolymers of 4‐benzyloxycarbonylphenyl acrylate with glycidyl methacrylate: Synthesis, characterization, reactivity ratios, and application as adhesive for leather Journal of Applied Polymer Science. ,vol. 91, pp. 3604- 3612 ,(2004) , 10.1002/APP.13594