Homopolymer and copolymers of 4‐benzyloxycarbonylphenyl acrylate with glycidyl methacrylate: Synthesis, characterization, reactivity ratios, and application as adhesive for leather

摘要: 4-Benzyloxycarbonylphenyl acrylate (BCPA) was prepared by reacting benzyl-4-hydroxy benzoate dissolved in methyl ethyl ketone with acryloyl chloride the presence of triethylamine. The homopolymer and copolymers BCPA glycidyl methacrylate (GMA) having different compositions were synthesized using benzoyl peroxide as a free-radical initiator at 70 ± 1°C. All polymers characterized FTIR, 1H-NMR, 13C-NMR spectroscopic techniques. solubility tested various polar nonpolar solvents. molecular weights (Mw Mn) polydispersity indices determined gel permeation chromatography. glass-transition temperatures increased increasing GMA content copolymer. Thermogravimetric analysis performed air showed that thermal stability copolymer content. Copolymer 1H-NMR analysis. monomer reactivity ratios application conventional linearization methods such Fineman–Ross (r1 = 0.5237; r2 1.9646), Kelen–Tudos 0.4996; 1.8741), extended 0.4652; 1.9046) well nonlinear error-in-variables model (EVM) method, computer program RREVM 0.4644; 1.8324). peel strength leather adhesives from also determined. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3604–3612,