MMZ NiY -Catalyzed Tsuji–Trost Type of Reaction: A Selective Mono/Bis Allylation of Dicarbonyl Compounds
作者： Samuthirarajan Senthilkumar , Cheirmakani Thangapriya , Raman Alagumurugayee , Mayilvasagam Kumarraja
DOI: 10.1007/S10562-017-2185-3
关键词:
摘要: An alternative method to Pd-catalyzed Tsuji–Trost reaction is developed and it provides a simpler route for the selective synthesis of broad range mono-/bis-allylated cinnamylated 1,3-dicarbonyl compounds using MMZNiY catalyst at room temperature. Product selectivity can be controlled by proper choice catalyst. The was also well characterized SEM, TEM, HRTEM, EDAX X-ray analysis. Other advantages like its ease preparation, functional tolerance reusability are highlighted.
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