Olefin oligomerization method involving a catalytic system based on organometallic complexes and a porous solid
作者： Pascal Raybaud , Herve Toulhoat , Theodorus De Bruin
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摘要: The present invention relates to a method of oligomerizing olefins M selectively oligomers Mn, involving catalytic system comprising at least one organometallic complex with metal groups 4 10 the periodic table molecular volume Vmo, and micro- or mesoporous solid whose average micropore diameter Φ is greater than equal Φmin defined as function (Vmo+nVmM), where n number monomeric strung together upon obtaining metallacycle intermediate VmM olefin.
lens.org 参考文章(11)
Robert Raja, John Thomas, Matthew Jones, Brian Johnson, Process for asymmetrically hydrogenating keto carboxylic esters ,(2004)
Johan Paul Smit, Harry van der Heijden, Arie van Zon, Eric Johannes Maria De Boer, Quoc An On, Transition metal complexes ,(2005)
Mohamed Eddaoudi, Nathaniel Rosi, Omar M. Yaghi, Jaheon Kim, Hailian Li, Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage ,(2002)
Omar M. Yaghi, Rahul Banerjee, Hideki Hayashi, Adsorptive gas separation of multi-component gases ,(2008)
Yu Guo, Xuequan Zhang, Weimin Dong, Organic–inorganic hybrid supported zirconocene catalysts for ethylene polymerization Journal of Molecular Catalysis A: Chemical. ,vol. 237, pp. 45- 49 ,(2005) , 10.1016/J.MOLCATA.2005.03.025
J Weitkamp, Zeolites and catalysis Solid State Ionics. ,vol. 131, pp. 175- 188 ,(2000) , 10.1016/S0167-2738(00)00632-9
Sven Tobisch, Tom Ziegler, Catalytic Linear Oligomerization of Ethylene to Higher α-Olefins: Insight into the Origin of the Selective Generation of 1-Hexene Promoted by a Cationic Cyclopentadienyl-Arene Titanium Active Catalyst Organometallics. ,vol. 22, pp. 5392- 5405 ,(2003) , 10.1021/OM0341247
Michèle O de Souza, Larissa R Rodrigues, Heloise O Pastore, Juan AC Ruiz, Léon Gengembre, Régis M Gauvin, Roberto F de Souza, None, A nano-organized ethylene oligomerization catalyst: Characterization and reactivity of the Ni(MeCN)6(BF4)2/[Al]-MCM-41/AlEt3 system Microporous and Mesoporous Materials. ,vol. 96, pp. 109- 114 ,(2006) , 10.1016/J.MICROMESO.2006.06.023
Eduardo J. Baralt, Ronald D. Knudsen, Brooke L. Small, Ronald G. Abbott, Steven D. Bridges, Bruce E. Kreischer, Methods of Preparation of an Olefin Oligomerization Catalyst ,(2005)
Patrick J. W. Deckers, Bart Hessen, Jan H. Teuben, Catalytic trimerization of ethene with highly active cyclopentadienyl-arene titanium catalysts Organometallics. ,vol. 21, pp. 5122- 5135 ,(2002) , 10.1021/OM020765A