The stereochemistry of sodium dithionite reductions of cyclic ketones
作者： A.Paul Krapcho , David A. Seidman
DOI: 10.1016/0040-4039(81)80048-2
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摘要: Abstract The stereochemistry of reduction several substituted cyclohexanones, norcamphor, and camphor by sodium dithionite (sodium hydrosulfite, Na 2 S O 4 ) in aqueous DMF solution has been studied. cyclohexanones yield mainly equatorial alcohols while the bicyclic ketones give endo alcohols.
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sci-hub.se 参考文章(3)
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Francisco Camps, Jos� Coll, Mag�n Riba, Stereochemistry of methylcyclohexanones reduction by sodium dithionite under conventional and phase transfer conditions Journal of the Chemical Society, Chemical Communications. pp. 1080- 1081 ,(1979) , 10.1039/C39790001080
John W. Huffman, William W. McWhorter, Dissolving metal reduction of cyclic ketones Journal of Organic Chemistry. ,vol. 10, pp. 594- 599 ,(1979) , 10.1021/JO01318A023