A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides
作者： Norio Miyaura , Kinji Yamada , Akira Suzuki
DOI: 10.1016/S0040-4039(01)95429-2
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摘要: Abstract The representative (E)-1-alkenyldisiamylboranes and (E)-1-alkenyl-1, 3, 2-benzodioxaboroles readily obtainable via hydroboration of 1-alkynes react with 1-alkenyl halides or 1-alkynyl halides in the presence of a catalytic amount of tetrakis (triphenylphosphine) palladium and base to give corresponding conjugated (E)-dienes or (E)-enynes with high regio-and stereospecificity in good yields, respectively.
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