Effect of pass deformation on microstructure, corrosion and electrochemical properties of aluminum alloy anodes for alkaline aluminum fuel cell applications

作者: Yong Zhang , Shuquan Liang , Athar Javed , Dikai Guan

DOI: 10.1007/S12540-013-3025-7

关键词:

摘要: The effect of pass deformation in rolling processes on the microstructure, corrosion resistance and electrochemical activity Al-Mg-Bi-Sn-Ga-In alloy anodes operated an alkaline solution (85 °C, 5 mol·L−1 NaOH with addition NaSnO3) current density 800 mA·cm−2 was investigated. To analyze microstructure aluminum anodes, we used scanning electron microscope, transmission microscope backscatter diffraction techniques. We also hydrogen evolution method testing techniques to investigate behavior anodes. results showed that uniform microstructures homogeneous distribution fine active segregated phases as well excellent performance were achieved by dynamic recrystallization under 40%. found (under 40%) had lowest rate (0.092 mL·min−1·cm−2) most negative electrode potential (−1.585 V).

参考文章(29)
W. Wilhelmsen, T. Arnesen, Ø. Hasvold, N.J. Størkersen, The electrochemical behaviour of AlIn alloys in alkaline electrolytes Electrochimica Acta. ,vol. 36, pp. 79- 85 ,(1991) , 10.1016/0013-4686(91)85182-7
Qi Gongtai, Qiu Yubin, The effect of heat treatment on element distribution and electrochemical properties of Al‐Zn‐In anodes Anti-Corrosion Methods and Materials. ,vol. 56, pp. 306- 309 ,(2009) , 10.1108/00035590911000278
Øistein Hasvold, Kjell Håvard Johansen, Ole Mollestad, Sissel Forseth, Nils Størkersen, The alkaline aluminium/hydrogen peroxide power source in the Hugin II unmanned underwater vehicle Journal of Power Sources. ,vol. 80, pp. 254- 260 ,(1999) , 10.1016/S0378-7753(98)00266-3
S. Abis, G. Barucca, P. Mengucci, Electron microscopy characterization of AlSn metal—metal matrix composites Journal of Alloys and Compounds. ,vol. 215, pp. 309- 313 ,(1994) , 10.1016/0925-8388(94)90859-1
M.L. Doche, F. Novel-Cattin, R. Durand, J.J. Rameau, Characterization of different grades of aluminum anodes for aluminum/air batteries Journal of Power Sources. ,vol. 65, pp. 197- 205 ,(1997) , 10.1016/S0378-7753(97)02473-7
E.I. Shkolnikov, A.Z. Zhuk, M.S. Vlaskin, Aluminum as energy carrier: Feasibility analysis and current technologies overview Renewable & Sustainable Energy Reviews. ,vol. 15, pp. 4611- 4623 ,(2011) , 10.1016/J.RSER.2011.07.091
William A Ferrando, Development of a novel composite aluminum anode Journal of Power Sources. ,vol. 130, pp. 309- 314 ,(2004) , 10.1016/J.JPOWSOUR.2003.11.036
H.B. Shao, J.M. Wang, X.Y. Wang, J.Q. Zhang, C.N. Cao, Anodic dissolution of aluminum in KOH ethanol solutions Electrochemistry Communications. ,vol. 6, pp. 6- 9 ,(2004) , 10.1016/J.ELECOM.2003.10.007
X.X. Zeng, J.M. Wang, Q.L. Wang, D.S. Kong, H.B. Shao, J.Q. Zhang, C.N. Cao, The effects of surface treatment and stannate as an electrolyte additive on the corrosion and electrochemical performances of pure aluminum in an alkaline methanol–water solution Materials Chemistry and Physics. ,vol. 121, pp. 459- 464 ,(2010) , 10.1016/J.MATCHEMPHYS.2010.02.006