2,4,6-Triazido-1,3,5-Triazine, 2,4,6-Triazidopyrimidine, and 2,4,6-Triazidopyridine as Precursors of Carbon Nitride Materials
作者： N. V. Chukanov , S. V. Chapyshev , V. V. Nedel’ko , V. V. Zakharov , N. N. Dremova
DOI: 10.1134/S1990793118010177
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摘要: The thermolysis of 2,4,6-triazido-1,3,5-triazine (I), 2,4,6-triazidopyrimidine (II), and 2,4,6-triazidopyridine (III) its products were studied by DSC, mass spectrometry, IR spectroscopy, electron microscopy. thermal transformations I gave planar nets formed polyconjugated C–N bonds arranged into bundle aggregates. product III consists low-molecular compounds has globular morphology. II resulted in a mixture both types, among which the dominant. relationship between structure I, II, kinetic characteristics these processes was discussed.
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