Determination of Water Loss Mechanism in Amine Terminous Amino Acids Using Laser Mass Spectrometry
作者： Kenneth J. Rosnack , Kasi V. Somayajula , Andrew G. Sharkey , Nancy J. Jensen , David M. Hercules
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摘要: The water loss process in Laser Mass Spectrometry of amine terminal amino acids was studied. Water is proposed to occur via a thermal decomposition mechanism for protonated acid forming lactam ring. magnitude the peak correlated with stability Semi-empirical MNDO calculations heat reaction ring and support correlation. substrate (matrix) appears have little effect on process; results are essentially same use different substrates sample preparation methods.
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