Expanding applications of copper-based metal–organic frameworks in catalysis: Oxidative C–O coupling by direct C–H activation of ethers over Cu2(BPDC)2(BPY) as an efficient heterogeneous catalyst
作者： Nam T.S. Phan , Phuong H.L. Vu , Tung T. Nguyen
DOI: 10.1016/J.JCAT.2013.06.006
关键词:
摘要: A crystalline porous metal–organic framework Cu 2 (BPDC) 2 (BPY) was synthesized and characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR) spectra, atomic absorption spectrophotometry (AAS), hydrogen temperature-programmed reduction (H 2-TPR), and nitrogen physisorption measurements. The Cu-MOF could be used as an efficient heterogeneous catalyst for the copper-catalyzed …
elsevier.com
sci-hub.se 参考文章(79)
P. Santhosh Kumar, G. Sathish Kumar, R. Arun Kumar, N. Veera Reddy, K. Rajender Reddy, Copper‐Catalyzed Oxidative Coupling of Carboxylic Acids with N,N‐Dialkylformamides: An Approach to the Synthesis of Amides European Journal of Organic Chemistry. ,vol. 2013, pp. 1218- 1222 ,(2013) , 10.1002/EJOC.201201544
Zhiping Li, Chao-Jun Li, Highly Efficient Copper-Catalyzed Nitro-Mannich Type Reaction: Cross-Dehydrogenative-Coupling between sp3 C−H Bond and sp3 C−H Bond Journal of the American Chemical Society. ,vol. 127, pp. 3672- 3673 ,(2005) , 10.1021/JA050058J
Lianhui Wang, Lutz Ackermann, Versatile Pyrrole Synthesis through Ruthenium(II)-Catalyzed Alkene C–H Bond Functionalization on Enamines Organic Letters. ,vol. 15, pp. 176- 179 ,(2013) , 10.1021/OL303224E
Elena Pérez-Mayoral, Zuzana Musilová, Barbara Gil, Bartosz Marszalek, Miroslav Položij, Petr Nachtigall, Jiri Čejka, Synthesis of quinolines via Friedländer reaction catalyzed by CuBTC metal–organic-framework Dalton Transactions. ,vol. 41, pp. 4036- 4044 ,(2012) , 10.1039/C2DT11978A
Zhiping Li, Chao-Jun Li, Catalytic enantioselective alkynylation of prochiral sp3 C-H bonds adjacent to a nitrogen atom. Organic Letters. ,vol. 6, pp. 4997- 4999 ,(2004) , 10.1021/OL047814V
A. Corma, H. García, F. X. Llabrés i Xamena, Engineering Metal Organic Frameworks for Heterogeneous Catalysis Chemical Reviews. ,vol. 110, pp. 4606- 4655 ,(2010) , 10.1021/CR9003924
Balaji D. Barve, Yang-Chang Wu, Mohamed El-Shazly, Da-Wei Chuang, Yu-Ming Chung, Yi-Hong Tsai, Shou-Fang Wu, Michal Korinek, Ying-Chi Du, Chi-Ting Hsieh, Jeh-Jeng Wang, Fang-Rong Chang, Synthesis of Carbamates by Direct C–H Bond Activation of Formamides European Journal of Organic Chemistry. ,vol. 2012, pp. 6760- 6766 ,(2012) , 10.1002/EJOC.201201160
Gunther Langhendries, Dirk E. De Vos, Gino V. Baron, Pierre A. Jacobs, Quantitative sorption experiments on Ti-zeolites and relation with α-olefin oxidation by H2O2 Journal of Catalysis. ,vol. 187, pp. 453- 463 ,(1999) , 10.1006/JCAT.1999.2608
Amarajothi Dhakshinamoorthy, Mercedes Alvaro, Hermenegildo Garcia, Metal organic frameworks as efficient heterogeneous catalysts for the oxidation of benzylic compounds with t-butylhydroperoxide Journal of Catalysis. ,vol. 267, pp. 1- 4 ,(2009) , 10.1016/J.JCAT.2009.08.001
Wen-Peng Mai, Hui-Hui Wang, Zhi-Cheng Li, Jin-Wei Yuan, Yong-Mei Xiao, Liang-Ru Yang, Pu Mao, Ling-Bo Qu, nBu4NI-catalyzed direct synthesis of α-ketoamides from aryl methyl ketones with dialkylformamides in water using TBHP as oxidant Chemical Communications. ,vol. 48, pp. 10117- 10119 ,(2012) , 10.1039/C2CC35279F