Fluoro-ketones VII. Synthesis of perfluoro mono- and di-ketones from perfluoro-grignard or lithium reagents and diethyl carbonate and diethyl oxalate
作者： Loomis S. Chen , Grace J. Chen , Christ Tamborski
DOI: 10.1016/S0022-1139(00)80935-5
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摘要: Abstract The reaction between perfluoroalkyl-Grignard or lithium compounds and diethyl carbonate has been investigated. Under appropriate conditions, symmetric asymmetric ketones can be prepared. reactions of the perfluoro- Grignard with oxalate yield keto-esters ketones.
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