Synergistic effects in the transition metal catalysed hydrogenation of commercial graphites promoted by Ca(NO3)2 and pretreated with O2 or CO2
作者： R. Dziembaj , W. Makowski , L. Chmielarz
DOI: 10.1016/0008-6223(96)00041-3
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摘要: Abstract The influence of Fe, Co, Ni and Ca nitrate additives on the gasification commercial graphite electrodes with hydrogen was characterized by TPR measurements. order catalytic activity has been established as > Co Fe. low temperature peaks at 300–400 °C appear preoxidized surfaces only. Ca, inactive alone, shows strong promotion hydrogen, especially in case catalyst. highest synergistic effect found for Co/Ca/CO2 activated sample. Samples CO2 show higher reactivity methane formation than samples O2.
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