Photoluminescence of silicon-vacancy defects in nanodiamonds of different chondrites

作者: I. I. Vlasov , A. A. Khomich , L. F. Semjonova , A. A. Shiryaev , A. V. Fisenko

DOI: 10.1111/MAPS.12450

关键词:

摘要: Photoluminescence spectra show that silicon impurity is present in lattice of some nanodiamond grains (ND) various chondrites as a silicon-vacancy (SiV) defect. The relative intensity the SiV band diamond-rich separates depends on chemical composition meteorites and size ND grains. strongest signal found for enriched small grains; thus, confirming our earlier conclusion defects preferentially reside smallest (≤2 nm) difference intensities luminescence individual are due to variable conditions thermal metamorphism their parent bodies and/or uneven sampling populations. Annealing air eliminates surface sp 2 -carbon; consequently, enhanced. Strong well-defined absorption defect promising feature locate cold (<250 °C) nanodiamonds space.

参考文章(56)
Tyrone L. Daulton, Extraterrestrial Nanodiamonds in the Cosmos Ultrananocrystalline Diamond. pp. 23- 78 ,(2006) , 10.1016/B978-081551524-1.50004-4
Alexander Ya. Vul', Characterization and Physical Properties of UNCD Particles Ultrananocrystalline Diamond. pp. 379- 404 ,(2006) , 10.1016/B978-081551524-1.50014-7
Alexander M Zaitsev, Optical properties of diamond ,(2001)
A.V. Fisenko, A.B. Verchovsky, C.T. Pillinger, L.F. Semenova, Noble gases in the grain-size fractions of presolar diamond from the Boriskino CM2 meteorite ,(2004)
A. E. Rubin, J. N. Grossman, G. R. Huss, Thermal Metamorphism in Chondrites mess. pp. 567- ,(2006)
C. S. Kochanek, Dust Formation in the Presence of Photons I: Evaporation Rates for Small Dust Grains arXiv: Solar and Stellar Astrophysics. ,(2014)
A. A. Shiryaev, I. I. Kulakova, J. Helbert, A. Maturilli, Infra-red reflectance and emissivity spectra of nanodiamonds arXiv: Materials Science. ,(2012) , 10.1080/00387010.2013.805420
K. Iakoubovskii, G.J. Adriaenssens, N.N. Dogadkin, A.A. Shiryaev, Optical characterization of some irradiation-induced centers in diamond Diamond and Related Materials. ,vol. 10, pp. 18- 26 ,(2001) , 10.1016/S0925-9635(00)00361-7
Z. R. Dai, J. P. Bradley, D. J. Joswiak, D. E. Brownlee, H. G. M. Hill, M. J. Genge, Possible in situ formation of meteoritic nanodiamonds in the early Solar System. Nature. ,vol. 418, pp. 157- 159 ,(2002) , 10.1038/NATURE00897
David F. Blake, Friedemann Freund, Kannan F. M. Krishnan, Charles J. Echer, Ruth Shipp, Theodore E. Bunch, Alexander G. Tielens, Robert J. Lipari, Crispin J. D. Hetherington, Sherwood Chang, The nature and origin of interstellar diamond. Nature. ,vol. 332, pp. 611- 613 ,(1988) , 10.1038/332611A0