Opto‐thermal spectroscopy of the benzene 4←0 C–H stretch overtone

作者: Mario Scotoni , Cristina Leonardi , Davide Bassi

DOI: 10.1063/1.461246

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摘要: The 4←0 C–H stretching overtone of benzene has been measured in a supersonic molecular beam by means the opto‐thermal technique. Several vibrational transitions contribute to absorption spectrum 11 400–11 550 cm−1 region. upper limit for homogeneous linewidth is found ≊17 cm−1.

参考文章(8)
Ralph H. Page, Y. R. Shen, Y. T. Lee, Local modes of benzene and benzene dimer, studied by infrared–ultraviolet double resonance in a supersonic beam Journal of Chemical Physics. ,vol. 88, pp. 4621- 4636 ,(1988) , 10.1063/1.453775
T. E. Gough, R. E. Miller, G. Scoles, Infrared laser spectroscopy of molecular beams Applied Physics Letters. ,vol. 30, pp. 338- 340 ,(1977) , 10.1063/1.89390
Josef Plíva, Alan S. Pine, Analysis of the 3-μm bands of benzene Journal of Molecular Spectroscopy. ,vol. 126, pp. 82- 98 ,(1987) , 10.1016/0022-2852(87)90079-8
Mario Scotoni, Andrea Boschetti, Nadia Oberhofer, Davide Bassi, The 3←0 CH stretch overtone of benzene: An optothermal study The Journal of Chemical Physics. ,vol. 94, pp. 971- 977 ,(1991) , 10.1063/1.460693
Edwin L. Sibert, James T. Hynes, William P. Reinhardt, Classical dynamics of highly excited CH and CD overtones in benzene and perdeuterobenzene Journal of Chemical Physics. ,vol. 81, pp. 1135- 1144 ,(1984) , 10.1063/1.447806
D. Bassi, A. Boschetti, M. Scotoni, Z. Zen, Molecular Beam Diagnostics by Means of Fast Superconducting Bolometer and Pulsed Infrared Laser Applied Physics B. ,vol. 26, pp. 99- 103 ,(1981) , 10.1007/BF01284909
K. V. Reddy, Donald F. Heller, Michael J. Berry, Highly vibrationally excited benzene: Overtone spectroscopy and intramolecular dynamics of C6H6, C6D6, and partially deuterated or substituted benzenes Journal of Chemical Physics. ,vol. 76, pp. 2814- 2837 ,(1982) , 10.1063/1.443384