Ferrocenyltrithiocarbonates : II. Synthesis and x-ray structure determination of diiron hexacarbonyl complexes
作者： Henri Patin , Gérard Mignani , Christian Mahé , Jean-Yves Le Marouille , Timothy G. Southern
DOI: 10.1016/S0022-328X(00)84685-9
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摘要: Abstract Ferrocenyltrithiocarbonates, I, react with Fe2(CO)9 to afford new types of binuclear complexes in which the diiron hexacarbonyl moiety is linked by two bridges resulting from insertion an iron atom into carbon-sulfur single bond. The X-ray structure determination μ-(thioferrocenylmethylmethane thiomethylene-C1, S2)-1,1,1,2,2,2-hexacarbonyl-μ-methylthioiron (FeFe) has been refined R = 0.037. Comparison and 13C data those starting materials are agreement a metallocarbene structure.
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sci-hub.se 参考文章(12)
Ernst A. Koerner von Gustorf, Ingrid Fischler, Friedrich-Wilhelm Grevels, The Organic chemistry of iron Academic Press. ,(1978)
Henri Patin, Gerard Mignani, Christian Mahe, Jean-Yves Le Marouille, Alain Benoit, Daniel Grandjean, Ferrocenyltrithiocarbonates : I. Direct access from α-ferrocenylcarbinols by a SNi mechanism. Absolute x-ray structure determination of (R)-ferrocenylmethylmethane S-methyl-trithiocarbonate Journal of Organometallic Chemistry. ,vol. 193, pp. 93- 103 ,(1980) , 10.1016/S0022-328X(00)86079-9
Guy Le Borgne, Daniel Grandjean, René Mathieu, René Poilblanc, Structural study of iron carbonyl derivatives: IV. Synthesis and crystal and molecular structure of syn-[μ-(SCH3)Fe(CO)2P(CH3)3]2 Journal of Organometallic Chemistry. ,vol. 131, pp. 429- 438 ,(1977) , 10.1016/S0022-328X(00)84420-4
F. H. Moore, Analytic constants for atomic scattering factors Acta Crystallographica. ,vol. 16, pp. 1169- 1175 ,(1963) , 10.1107/S0365110X63003054
W.K. Dean, D.G. Vanderveer, A complex with a bridging thiocarboxamido group: the crystal structure of Fe4(CO)12S(CSNMe2)(CNMe2) Journal of Organometallic Chemistry. ,vol. 146, pp. 143- 149 ,(1978) , 10.1016/S0022-328X(00)91441-4
G. Germain, P. Main, M. M. Woolfson, The application of phase relationships to complex structures. III. The optimum use of phase relationships Acta Crystallographica Section A. ,vol. 27, pp. 368- 376 ,(1971) , 10.1107/S0567739471000822
Gerhard N. Schrauzer, H. N. Rabinowitz, Jo Ann K. Frank, Iain C. Paul, Stabilization of a thioketocarbene through .pi.-complex formation. Synthesis and structure of trihapto-1,2-diphenylthioketocarbene-hexacarbonyldiiron Journal of the American Chemical Society. ,vol. 92, pp. 212- 214 ,(1970) , 10.1021/JA00704A043
L. E. McCandlish, G. H. Stout, L. C. Andrews, Statistics of derived intensities Acta Crystallographica Section A. ,vol. 31, pp. 245- 249 ,(1975) , 10.1107/S0567739475000496
H. Patin, G. Minani, R. Dabard, A. Benoit, Complexation of organic xanthates by carbonyliron identification of new dinuclear derivatives Journal of Organometallic Chemistry. ,vol. 168, ,(1979) , 10.1016/S0022-328X(00)92005-9
G. Mignani, H. Patin, R. Dabard, Synthesis and properties of alkoxyalkylidinetricobalt nonacarbonyl cluster complexes Journal of Organometallic Chemistry. ,vol. 169, ,(1979) , 10.1016/S0022-328X(00)81468-0