A complex with a bridging thiocarboxamido group: the crystal structure of Fe4(CO)12S(CSNMe2)(CNMe2)
作者： W.K. Dean , D.G. Vanderveer
DOI: 10.1016/S0022-328X(00)91441-4
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摘要: Abstract The structure of the compound Fe 4 (CO) 12 S(CSNMe 2 )(CNMe ) has been determined by X-ray crystallography. crystallizes in space group P 1 / c with four molecules a unit cell dimensions 8.840(2), b 20.174(9), 16.856(5)A, β 114.82(3)°. Full-matrix least-squares refinement 2881 counter data yielded R = 0.046. molecule consists two 6 units bridged thiocarboxamido and immoniocarbene ligands common bridging sulfur atom. this is compared those related detailed comparison made bonding properties ligand chelating configurations.
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