1D and 2D Nuclear magnetic resonance of new silver(I) complexes with achiral and chiral bases as ligands: Crystal structure of [Ag{(S)-(6-CH3)C5H3N-CHN-C*H(α-CH3)C6H5}(PPh3)2](O3SCF3)

作者: Olga Cifuentes , Raúl Contreras , Antonio Laguna , Olga Crespo

DOI: 10.1016/J.ICA.2011.09.033

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摘要: Abstract Treatment of equimolar amounts substituted aniline or amine with benzaldehyde leads to the corresponding achiral chiral Schiff bases (L). The reaction [Ag(O3SCF3)(PPh3)] preparation three four coordinated cationic complexes, [Ag(k1-L)(PPh3)n]+ (n = 1 2) which have been characterized by IR, 1D and 2D NMR spectroscopy. crystal structure [Ag{(S)-(6-CH3)C5H3N-CHN-C*H(α-CH3)C6H5}(PPh3)2](O3SCF3) is reported.

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