The excitation wavelength dependent fluorescence of porphyrins
作者： Mahesh Uttamlal , A. Sheila Holmes-Smith
DOI: 10.1016/J.CPLETT.2008.02.012
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摘要: Abstract Spectroscopic studies of meso-tetraphenylporphyrin and other meso-substituted porphyrin derivatives have revealed a dual fluorescence emission process. The first is the usual 1(π←π∗) transition. second alternative process proposed to arise following tautomerism inner macrocyclic hydrogen atoms via an atom tunnelling This occurs when exciting at virtually all wavelengths in Q band region but, its most intense Qx(0,0) not observed Soret maximum, i.e., spectrum TPP dependent on excitation wavelength.
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G. Schapira, J. Elion, The porphyrins, physical chemistry, part B, Vol. IV, par David Dolphin (Academic Press, New York). Biochimie. ,vol. 62, ,(1980) , 10.1016/S0300-9084(80)80181-7
Charles Weiss, Hiroshi Kobayashi, Martin Gouterman, Spectra of porphyrins: Part III. Self-consistent molecular orbital calculations of porphyrin and related ring systems Journal of Molecular Spectroscopy. ,vol. 16, pp. 415- 450 ,(1965) , 10.1016/0022-2852(65)90132-3
Martin Gouterman, Georges H. Wagnière, Lawrence C. Snyder, Spectra of porphyrins: Part II. Four orbital model Journal of Molecular Spectroscopy. ,vol. 11, pp. 108- 127 ,(1963) , 10.1016/0022-2852(63)90011-0
J. Spencer Baskin, Hua-Zhong Yu, Ahmed H. Zewail, Ultrafast Dynamics of Porphyrins in the Condensed Phase: I. Free Base Tetraphenylporphyrin † Journal of Physical Chemistry A. ,vol. 106, pp. 9837- 9844 ,(2002) , 10.1021/JP020398G
Martin Gouterman, Study of the Effects of Substitution on the Absorption Spectra of Porphin The Journal of Chemical Physics. ,vol. 30, pp. 1139- 1161 ,(1959) , 10.1063/1.1730148
Zheng-Li Cai, Maxwell J. Crossley, Jeffrey R. Reimers, Rika Kobayashi, Roger D. Amos, Density Functional Theory for Charge Transfer: The Nature of the N-Bands of Porphyrins and Chlorophylls Revealed through CAM-B3LYP, CASPT2, and SAC-CI Calculations Journal of Physical Chemistry B. ,vol. 110, pp. 15624- 15632 ,(2006) , 10.1021/JP063376T
Harold N. Fonda, Julanna V. Gilbert, Russell A. Cormier, Julian R. Sprague, Keiko Kamioka, John S. Connolly, Spectroscopic, photophysical, and redox properties of some meso-substituted free-base porphyrins The Journal of Physical Chemistry. ,vol. 97, pp. 7024- 7033 ,(1993) , 10.1021/J100129A017
Adam Lukaszewicz, Jerzy Karolczak, Dorota Kowalska, Andrzej Maciejewski, Marcin Ziolek, Ronald P. Steer, Photophysical processes in electronic states of zinc tetraphenyl porphyrin accessed on one- and two-photon excitation in the soret region principles and practice of constraint programming. ,vol. 331, pp. 359- 372 ,(2007) , 10.1016/J.CHEMPHYS.2006.11.006
Alsoph H. Corwin, Arthur B. Chivvis, Robert W. Poor, David G. Whitten, Earl Wayne. Baker, Porphyrin studies. XXXVII. The interpretation of porphyrin and metalloporphyrin spectra Journal of the American Chemical Society. ,vol. 90, pp. 6577- 6583 ,(1968) , 10.1021/JA01026A001
Martin Gouterman, Spectra of porphyrins Journal of Molecular Spectroscopy. ,vol. 6, pp. 138- 163 ,(1961) , 10.1016/0022-2852(61)90236-3