Spin-crossover-induced Mott transition and the other scenarios of metallization in 3 d n metal compounds

作者: I. S. Lyubutin , S. G. Ovchinnikov , A. G. Gavriliuk , V. V. Struzhkin

DOI: 10.1103/PHYSREVB.79.085125

关键词:

摘要: A different 'Hubbard energy control' mechanism of the insulator-metal transition (IMT) in Mott-Hubbard insulators is discussed. This can be initiated by lattice compression and it driven a spin crossover 3d{sup 5} ions from high-spin state to low-spin state. The suppresses effective Hubbard parameter U{sub eff} down value enabling according Mott eff}/W{approx}1. classification possible scenarios metallization other n} metal compounds also performed.

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