An “Open Cube” Lithium Chloride Tetramer Containing Azetidine Ligands
作者： Alexander Jockisch , Hubert Schmidbaur
DOI: 10.1021/IC9900307
关键词:
摘要: Lithium chloride generated in the 1:4 reaction between carbon tetrachloride and lithium azetidinide is trapped as a tetramer by azetidine its dimer N-(3-aminopropyl)azetidine form of an “open cube”, new structural variant among (LiCl)n oligomers predicted previous theoretical calculations. In orthorhombic lattice, tetranuclear units are stacked along polar z-axis via four intermolecular N−H- - -Cl hydrogen bonds.
acs.org
sci-hub.se 参考文章(8)
Paul von R. Schleyer, Anne-Marie Sapse, Lithium chemistry : a theoretical and experimental overview Wiley. ,(1995)
Etienne H. Schacht, Eric J. Goethals, Cationic polymerization of cyclic amines, 3. Polymerization of azetidine Macromolecular Chemistry and Physics. ,vol. 175, pp. 3447- 3459 ,(1974) , 10.1002/MACP.1974.021751211
Shunichi Murahashi, Noriaki Yoshimura, Tatsuo Tsumiyama, Takeyuki Kojima, Catalytic alkyl group exchange reaction of primary and secondary amines Journal of the American Chemical Society. ,vol. 105, pp. 5002- 5011 ,(1983) , 10.1021/JA00353A025
Hubert Schmidbaur, Annette Schier, Ulrich Schubert, Synthese und Kristallstruktur von Di‐μ3‐bromo‐di‐μ3‐cyclo‐propyl‐tetralithium‐Tetrakis(diethylether): Ein Beitrag zum Problem des „Salz‐Effekts”︁ bei Lithiumorganylen Chemische Berichte. ,vol. 116, pp. 1938- 1946 ,(1983) , 10.1002/CBER.19831160521
Colin L. Raston, Claire R. Whitaker, Allan H. White, Lewis base adducts of main group 1 metal compounds. 7. The lithium-coinage-metal parallel: novel adducts of lithium(I) bromide and iodide with 2,6-dimethylpyridine Inorganic Chemistry. ,vol. 28, pp. 163- 165 ,(1989) , 10.1021/IC00300A037
Daniele Hoffmann, Andrea Dorigo, Paul von Schleyer, Hubert Reif, Dietmar Stalke, George M. Sheldrick, Erwin Weiss, Maren Geissler, The Bicyclic Structure of a Novel TMEDA-Solvated Lithium Chloride Tetramer [(LiCl)4.cntdot.3.5TMEDA]2: X-ray Structural Analysis and MO Investigations Inorganic Chemistry. ,vol. 34, pp. 262- 269 ,(1995) , 10.1021/IC00105A042
CL Raston, WT Robinson, BW Skelton, CR Whitaker, AH White, Lewis-Base Adducts of Main Group 1 Metal-Compounds. XIII. Synthesis and Structures of Some Pyridine Base Lithium Bromide and Iodide Adducts Australian Journal of Chemistry. ,vol. 43, pp. 1163- 1173 ,(1990) , 10.1071/CH9901163
Jacob Szmuszkovicz, Michael P. Kane, Lloyd G. Laurian, Constance G. Chidester, Terrence A. Scahill, New synthesis of azetidine Journal of Organic Chemistry. ,vol. 13, pp. 3562- 3564 ,(1981) , 10.1021/JO00330A043