Exploring the influence of designer surfactant hydrophobicity in key CC/CN bond forming reactions
作者： Singarajanahalli Mundarinti Krishna Reddy , Jagatheeswaran Kothandapani , Megarajan Sengan , Anbazhagan Veerappan , Subramaniapillai Selva Ganesan
DOI: 10.1016/J.MCAT.2019.01.006
关键词:
摘要: Abstract Designer micellar medium was explored for the transformation of diverse anilines to corresponding densely substituted biologically relevant skatole derivatives in an aqueous via 5-exo-trig cyclization reaction. The scope reaction extended intermolecular Csp2-Csp2 and Csp2-N bond forming reactions water. Systematic investigations revealed that altering hydrophobicity surfactant influences yield both C N
sci-hub.se 参考文章(36)
Bruce H. Lipshutz, Benjamin R. Taft, Alexander R. Abela, Subir Ghorai, Arkady Krasovskiy, Christophe Duplais, Catalysis in the Service of Green Chemistry: Nobel Prize-Winning Palladium-Catalysed Cross-Couplings, Run in Water at Room Temperature: Heck, Suzuki-Miyaura and Negishi reactions carried out in the absence of organic solvents, enabled by micellar catalysis. Platinum Metals Review. ,vol. 56, pp. 62- 74 ,(2012) , 10.1595/147106712X629761
Alex G. Therien, Charles M. Deber, Interhelical Packing in Detergent Micelles: FOLDING OF A CYSTIC FIBROSIS TRANSMEMBRANE CONDUCTANCE REGULATOR CONSTRUCT Journal of Biological Chemistry. ,vol. 277, pp. 6067- 6072 ,(2002) , 10.1074/JBC.M110264200
Seralathan Janani, Priscilla Stevenson, Anbazhagan Veerappan, Activity of catalytic silver nanoparticles modulated by capping agent hydrophobicity Colloids and Surfaces B: Biointerfaces. ,vol. 117, pp. 528- 533 ,(2014) , 10.1016/J.COLSURFB.2014.03.008
Bruce H. Lipshutz, Alexander R. Abela, Micellar Catalysis of Suzuki−Miyaura Cross-Couplings with Heteroaromatics in Water Organic Letters. ,vol. 10, pp. 5329- 5332 ,(2008) , 10.1021/OL801712E
Bruce H. Lipshutz, Subir Ghorai, Alexander R. Abela, Ralph Moser, Takashi Nishikata, Christophe Duplais, Arkady Krasovskiy, Ricky D. Gaston, Robert C. Gadwood, TPGS-750-M: a second-generation amphiphile for metal-catalyzed cross-couplings in water at room temperature. Journal of Organic Chemistry. ,vol. 76, pp. 4379- 4391 ,(2011) , 10.1021/JO101974U
Barrie C. C. Cantello, Michael A. Cawthorne, Graham P. Cottam, Peter T. Duff, David Haigh, Richard M. Hindley, Carolyn A. Lister, Stephen A. Smith, Peter L. Thurlby, [[omega-(Heterocyclylamino)alkoxy]benzyl]-2,4-thiazolidinediones as potent antihyperglycemic agents. Journal of Medicinal Chemistry. ,vol. 37, pp. 3977- 3985 ,(1994) , 10.1021/JM00049A017
Ricardo C. Pasquali, Gustavo F. Helguera, “True” Hydrophilic-Lipophilic Balance of Polyoxyethylene Fatty Acid Esters Nonionic Surfactants Journal of Dispersion Science and Technology. ,vol. 34, pp. 716- 721 ,(2013) , 10.1080/01932691.2011.653922
Marina Cvjetko Bubalo, Senka Vidović, Ivana Radojčić Redovniković, Stela Jokić, Green Solvents for Green Technologies Journal of Chemical Technology & Biotechnology. ,vol. 90, pp. 1631- 1639 ,(2015) , 10.1002/JCTB.4668
Eiji KUMAZAWA, Kenji HIROTANI, S. Clifford BURFORD, Keiichi KAWAGOE, Tamotsu MIWA, Ikuo MITSUI, Akio EJIMA, Synthesis and Antitumor Activity of Novel Benzophenone Derivatives Chemical & Pharmaceutical Bulletin. ,vol. 45, pp. 1470- 1474 ,(1997) , 10.1248/CPB.45.1470
Oktay K. Gasymov, Ben J. Glasgow, ANS fluorescence: potential to augment the identification of the external binding sites of proteins. Biochimica et Biophysica Acta. ,vol. 1774, pp. 403- 411 ,(2007) , 10.1016/J.BBAPAP.2007.01.002