Elucidation of structural changes and concentration fluctuations in binary mixtures using new thermodynamic relations
作者： Y Tsuchiya
DOI: 10.1088/0953-8984/11/3/002
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摘要: The thermodynamics associated with structural changes in binary mixtures has been examined search of relations which connect Darken stability or the concentration-concentration fluctuations to thermodynamic response functions. New have derived. These are counterpart Ehrenfest an extended form for second order phase transitions mixtures. It proved that change inevitably causes instability a mixture respect concentration fluctuations. new make it possible brought about by can be evaluated terms
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