Grafting cellulose acetate with ionic liquids for biofuel purification membranes : Influence of the anion.
作者： Faten Hassan Hassan Abdellatif , Jérôme Babin , Carole Arnal-Herault , Laurent David , Anne Jonquieres
DOI: 10.1016/J.CARBPOL.2018.05.008
关键词:
摘要: Abstract Membranes made from cellulose acetate grafted with imidazolium or ammonium ionic liquids (ILs) containing different anions were considered for ethyl tert-butyl ether biofuel purification by pervaporation. The new cellulosic materials obtained after bromide (Br−) exchange (Tf2N−, BF4−, AcO−). IL structure-membrane property relationships revealed that the membrane properties strongly improved varying anion structure, molecular size and hydrogen bonding acceptor ability β in Kamlet-Taft polarity scale. AcO− combined highest parameter big cation/anion sizes finally led to best a normalized pervaporation flux of 0.41 kg/h m2 (almost 20 times virgin acetate) reference thickness 5 μm permeate ethanol content 100%. Such thus corresponded an outstanding separation factor at 50 °C.
sci-hub.se 参考文章(51)
Stefan Spange, Ralf Lungwitz, Alexander Schade, Correlation of molecular structure and polarity of ionic liquids Journal of Molecular Liquids. ,vol. 192, pp. 137- 143 ,(2014) , 10.1016/J.MOLLIQ.2013.06.016
Lloyd M. Robeson, The upper bound revisited Journal of Membrane Science. ,vol. 320, pp. 390- 400 ,(2008) , 10.1016/J.MEMSCI.2008.04.030
Aleksandra Jeličić, Nuria García, Hans-Gerd Löhmannsröben, Sabine Beuermann, Prediction of the Ionic Liquid Influence on Propagation Rate Coefficients in Methyl Methacrylate Radical Polymerizations Based on Kamlet-Taft Solvatochromic Parameters Macromolecules. ,vol. 42, pp. 8801- 8808 ,(2009) , 10.1021/MA9017907
Thomas V. Doherty, Mauricio Mora-Pale, Sage E. Foley, Robert J. Linhardt, Jonathan S. Dordick, Ionic liquid solvent properties as predictors of lignocellulose pretreatment efficacy Green Chemistry. ,vol. 12, pp. 1967- 1975 ,(2010) , 10.1039/C0GC00206B
A. Plaza, G. Merlet, A. Hasanoglu, M. Isaacs, J. Sanchez, J. Romero, Separation of butanol from ABE mixtures by sweep gas pervaporation using a supported gelled ionic liquid membrane: Analysis of transport phenomena and selectivity Journal of Membrane Science. ,vol. 444, pp. 201- 212 ,(2013) , 10.1016/J.MEMSCI.2013.04.034
Quang-Trong Nguyen, Christian Léger, Philippe Billard, P. Lochon, Novel membranes made from a semi‐interpenetrating polymer network for ethanol–ETBE separation by pervaporation Polymers for Advanced Technologies. ,vol. 8, pp. 487- 495 ,(1997) , 10.1002/(SICI)1099-1581(199708)8:8<487::AID-PAT656>3.0.CO;2-R
Ekaterina I Izgorodina, None, Towards large-scale, fully ab initio calculations of ionic liquids. Physical Chemistry Chemical Physics. ,vol. 13, pp. 4189- 4207 ,(2011) , 10.1039/C0CP02315A
Michiaki MATSUMOTO, Yuuki MURAKAMI, Kazuo KONDO, Separation of 1-Butanol by Pervaporation Using Polymer Inclusion Membranes Containing Ionic Liquids Solvent Extraction Research and Development-japan. ,vol. 18, pp. 75- 83 ,(2011) , 10.15261/SERDJ.18.75
Mortimer J. Kamlet, R. W. Taft, The solvatochromic comparison method. I. The .beta.-scale of solvent hydrogen-bond acceptor (HBA) basicities Journal of the American Chemical Society. ,vol. 98, pp. 377- 383 ,(1976) , 10.1021/JA00418A009
Mortimer J. Kamlet, Jose Luis M. Abboud, Michael H. Abraham, R. W. Taft, Linear solvation energy relationships. 23. A comprehensive collection of the solvatochromic parameters, .pi.*, .alpha., and .beta., and some methods for simplifying the generalized solvatochromic equation Journal of Organic Chemistry. ,vol. 48, pp. 2877- 2887 ,(1983) , 10.1021/JO00165A018