Significance of porous structure on degradatin of 2 2′ dichloro diethyl sulphide and 2 chloroethyl ethyl sulphide on the surface of vanadium oxide nanostructure
作者： Beer Singh , T.H. Mahato , A.K. Srivastava , G.K. Prasad , K. Ganesan
DOI: 10.1016/J.JHAZMAT.2011.02.003
关键词:
摘要: Abstract Degradation of the king chemical warfare agent, 2 2′ dichloro diethyl sulphide (HD), and its simulant chloroethyl ethyl (CEES) were investigated on surface porous vanadium oxide nanotubes at room temperature (30 ± 2 °C). Reaction kinetics was monitored by GC-FID technique reaction products characterized GC-MS. Data indicates that HD degraded faster relative to CEES inside solid decontaminant compared reported liquid phase degradation HD. explores role hydrolysis, elimination oxidation reactions in detoxification first order rate constant t1/2 calculated be 0.026 h−1, 26.6 h for 0.052 h−1, 13.24 h In this report explained basis structure.
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