High- Content, Well- Dispersed. gamma-Fe-2 O-3 Nanoparticles Encapsulated in Macroporous Silica with Superior Arsenic Removal Performance

作者: Jie Yang , Hongwei Zhang , Meihua Yu , Irene Emmanuelawati , Jin Zou

DOI: 10.1002/ADFM.201302561

关键词:

摘要: Novel composites of iron oxide encapsulated in macroporous silica with excellent arsenic adsorption performance have been successfully developed. Macroporous foams large pore sizes approximate to 100 nm and a high volume 1.6 cm(3) g(-1) are chosen as the porous matrix. Electron tomography technique confirms that -Fe2O3 nanoparticles an average particle size 6 spatially well-dispersed anchored on walls at even content 34.8 wt%, rather than forming aggregates inside pores or external surface. The open large-pore structure, loading amount, non-aggregated nature lead increased sites thus capacities both As (V) (III) without pre-treatment (248 320 mg g(-1), respectively). Moreover, can reduce concentration from 2 g L-1. It is also demonstrated be applied household drinking water treatment device, which continuously treat 20 L wastewater containing effluent lower World Health Organization standard.

参考文章(60)
Applications in Inorganic Chemistry John Wiley & Sons, Inc.. pp. 149- 354 ,(2008) , 10.1002/9780470405840.CH2
Kun Qian, Jingjing Wan, Fang Liu, Hubert H. Girault, Baohong Liu, Chengzhong Yu, A Phospho-Directed Macroporous Alumina−Silica Nanoreactor with Multi-Functions ACS Nano. ,vol. 3, pp. 3656- 3662 ,(2009) , 10.1021/NN900739Z
M Prassas, J Phalippou, L.L Hench, J Zarzycki, Preparation of xNa2O−(1−x)SiO2 gels for the gel-glass process: I. Atmospheric effect on the structural evolution of the gels Journal of Non-crystalline Solids. ,vol. 48, pp. 79- 95 ,(1982) , 10.1016/0022-3093(82)90247-2
Emma M. E. Kristensen, Fredrik Nederberg, Håkan Rensmo, Tim Bowden, Jöns Hilborn, Hans Siegbahn, Photoelectron spectroscopy studies of the functionalization of a silicon surface with a phosphorylcholine-terminated polymer grafted onto (3-aminopropyl)trimethoxysilane. Langmuir. ,vol. 22, pp. 9651- 9657 ,(2006) , 10.1021/LA060586O
John F Ferguson, Jerome Gavis, A review of the arsenic cycle in natural waters Water Research. ,vol. 6, pp. 1259- 1274 ,(1972) , 10.1016/0043-1354(72)90052-8
R. P. Netterfield, P. J. Martin, C. G. Pacey, W. G. Sainty, D. R. McKenzie, G. Auchterlonie, Ion-assisted deposition of mixed Tio2-Sio2 films Journal of Applied Physics. ,vol. 66, pp. 1805- 1809 ,(1989) , 10.1063/1.344352
John Kathi, K. Y. Rhee, Surface modification of multi-walled carbon nanotubes using 3-aminopropyltriethoxysilane Journal of Materials Science. ,vol. 43, pp. 33- 37 ,(2008) , 10.1007/S10853-007-2209-2
C. T. Yavuz, J. T. Mayo, W. W. Yu, A. Prakash, J. C. Falkner, S. Yean, L. Cong, H. J. Shipley, A. Kan, M. Tomson, D. Natelson, V. L. Colvin, Low-Field Magnetic Separation of Monodisperse Fe3O4 Nanocrystals Science. ,vol. 314, pp. 964- 967 ,(2006) , 10.1126/SCIENCE.1131475
Mark L. Miller, Richard W. Linton, X-ray photoelectron spectroscopy of thermally treated silica (SiO2) surfaces Analytical Chemistry. ,vol. 57, pp. 2314- 2319 ,(1985) , 10.1021/AC00289A033