Composite Silica Particles Using a Mixture of Organosilane Monomers

作者: Dong Il Han , Hoe Jin Hah , Hong-Woo Park , Sang Man Koo

DOI: 10.1007/S10971-004-5763-Y

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摘要: Composite silica particles were synthesized by a two-step (acid-base) process in an aqueous solution with mixture of organoalkoxysilane monomers. The separates the hydrolysis and condensation procedures to easily control rate. In this study, silane monomers used phenyltrimethoxysilane (PTMS), vinyltrimethoxysilane (VTMS), methyltrimethoxysilane (MTMS), tetraethyl-orthosilicate (TEOS). physical properties resultant composite investigated change molar ratio size increased increasing RaSi(OR)3/RbSi(OR)3 or RaSi(OR)3/TEOS (Ra: phenyl; Rb: vinyl, methyl).

参考文章(8)
C. Jeffrey Brinker, George W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing ,(1990)
Gerhard Schottner, Hybrid Sol−Gel-Derived Polymers: Applications of Multifunctional Materials Chemistry of Materials. ,vol. 13, pp. 3422- 3435 ,(2001) , 10.1021/CM011060M
John N. Hay, David Porter, Hema M. Raval, A versatile route to organically-modified silicas and porous silicas via the non-hydrolytic sol–gel process Journal of Materials Chemistry. ,vol. 10, pp. 1811- 1818 ,(2000) , 10.1039/A908900D
B.M. De Witte, D. Commers, J.B. Uytterhoeven, Distribution of organic groups in silica gels prepared from organo-alkoxysilanes Journal of Non-Crystalline Solids. ,vol. 202, pp. 35- 41 ,(1996) , 10.1016/0022-3093(96)00171-8
Hoe Jin Hah, Jung Soo Kim, Byung Jun Jeon, Sang Man Koo, Yong Eun Lee, Simple preparation of monodisperse hollow silica particles without using templates Chemical Communications. pp. 1712- 1713 ,(2003) , 10.1039/B301521A
J. E. Mark, Ceramic‐reinforced polymers and polymer‐modified ceramics Polymer Engineering and Science. ,vol. 36, pp. 2905- 2920 ,(1996) , 10.1002/PEN.10692
Jae Young Choi, Chong Hee Kim, Do Kyung Kim, Formation and Characterization of Monodisperse, Spherical Organo‐Silica Powders from Organo‐Alkoxysilane‐Water System Journal of the American Ceramic Society. ,vol. 81, pp. 1184- 1188 ,(2005) , 10.1111/J.1151-2916.1998.TB02466.X