Free radicals in catalytic oxidation of light alkanes: kinetic and thermochemical aspects
作者： Mikhail Yu. Sinev
DOI: 10.1016/S0021-9517(02)00116-1
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摘要: Abstract The kinetic and thermochemical analyses of the catalytic oxidation C 1 4 alkanes indicate that overall reaction network includes both homogeneous heterogeneous elementary reactions free radicals. Two parameters oxide catalysts, affinity surface active site E [O H] to a hydrogen atom oxygen binding energy [O] , are main factors determining features process. possible contribution radical some metal-catalyzed processes (steam reforming, partial total methane) is analyzed. Trends in studies chemistry radicals development innovative light alkane transformation into valuable products discussed.
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