Electrochemical and Corrosion Behavior of Nanocrystalline TiNi-Based Alloys and Composite

作者: M. Balcerzak , M. Jurczyk

DOI: 10.12693/APHYSPOLA.126.888

关键词:

摘要: In this work TiNi-based nanocrystalline alloys and composite were produced by mechanical alloying process with subsequent annealing at 750 ◦C for 0.5 h. Mechanical was performed in a SPEX 8000 Mixer Mill. TiNi alloy chemically modi ed Ag elemental powder. Silver content equaled 5 wt%. X-ray di raction analyses revealed formation of main phase after annealing. Additionally, two minor phases Ti2Ni TiNi3 detected unmodi alloy. Crystallites obtained powders nanosized. Corrosion electrochemical measurements 6 M KOH solution. All synthesized materials used as negative electrode Ni-MHx batteries. addition positively ects on stability discharge capacity during charge/discharge tests.

参考文章(7)
Robert A. Varin, Tomasz Czujko, Zbigniew S. Wronski, Nanomaterials for Solid State Hydrogen Storage ,(2008)
M. Balcerzak, M. Nowak, J. Jakubowicz, M. Jurczyk, Electrochemical behavior of nanocrystalline TiNi doped by MWCNTs and Pd Renewable Energy. ,vol. 62, pp. 432- 438 ,(2014) , 10.1016/J.RENENE.2013.07.031
R.-J. Shih, Y.Oliver Su, T.-P. Perng, Hydrogenation properties of a nonbreakable electrode made of ZrMn0.6V0.2Co0.1Ni1.2 and Ag Journal of Alloys and Compounds. ,vol. 353, pp. 283- 288 ,(2003) , 10.1016/S0925-8388(02)01294-X
Liu Jian, Gao Xueping, Song Deying, Zhang Yunshi, Ye Shihai, The characteristics of the microencapsulated TiNi alloys and their electrodes Journal of Alloys and Compounds. ,vol. 231, pp. 852- 855 ,(1995) , 10.1016/0925-8388(95)01771-2
Chang Bo Jung, Kyung Sub Lee, Electrode characteristics of metal hydride electrodes prepared by mechanical alloying Journal of Alloys and Compounds. ,vol. 253, pp. 605- 608 ,(1997) , 10.1016/S0925-8388(96)03044-7
C.S. Wang, Y.Q. Lei, Q.D. Wang, Effects of Nb and Pd on the electrochemical properties of a Ti-Ni hydrogen-storage electrode Journal of Power Sources. ,vol. 70, pp. 222- 227 ,(1998) , 10.1016/S0378-7753(97)02674-8
E. Jankowska, M. Makowiecka, M. Jurczyk, Electrochemical performance of sealed NiMH batteries using nanocrystalline TiNi-type hydride electrodes Renewable Energy. ,vol. 33, pp. 211- 215 ,(2008) , 10.1016/J.RENENE.2007.05.026