Insights on [BMIM][BF4] and [BMIM][PF6] ionic liquids and their binary mixtures with acetone and acetonitrile

摘要: Abstract The properties of ionic liquid plus acetone or acetonitrile mixtures were studied from the macro and microscopic levels by measurement relevant thermophysical through molecular modelling studies. considered in whole composition range analysed terms possible hydrogen bonding between ions with solvents. reported results show how large non-ideality these systems stands on high affinity for imidazolium bond donor sites, which allow competition corresponding anions sites specially but not limited to solvent rich mixtures. quantify relevance – mixtures, can be fine-tuned amounts cosolvent present mixture as a mechanism control mixed fluids organization.