A Cofacially Stacked Electron-Deficient Small Molecule with a High Electron Mobility of over 10 cm2V−1s−1in Air

作者: Jin-Hu Dou , Yu-Qing Zheng , Ze-Fan Yao , Ting Lei , Xingxing Shen

DOI: 10.1002/ADMA.201503803

关键词:

摘要: A strong, electron-deficient small molecule, F-4-BDOPV, has a lowest unoccupied molecular orbital (LUMO) level down to -4.44 eV and exhibits cofacial packing in single crystals. These features provide F-4-BDOPV with good ambient stability large charge-transfer integrals for electrons, leading high electron mobility of up 12.6 cm(2) V-1 s(-1) air.

参考文章(48)
Tao He, Matthias Stolte, Christian Burschka, Nis Hauke Hansen, Thomas Musiol, Daniel Kälblein, Jens Pflaum, Xutang Tao, Jochen Brill, Frank Würthner, Single-crystal field-effect transistors of new Cl 2 -NDI polymorph processed by sublimation in air Nature Communications. ,vol. 6, pp. 5954- ,(2015) , 10.1038/NCOMMS6954
John E Anthony, Antonio Facchetti, Martin Heeney, Seth R Marder, Xiaowei Zhan, n-Type organic semiconductors in organic electronics. Advanced Materials. ,vol. 22, pp. 3876- 3892 ,(2010) , 10.1002/ADMA.200903628
Jui-Fen Chang, Tomo Sakanoue, Yoann Olivier, Takafumi Uemura, Marie-Beatrice Dufourg-Madec, Stephen G. Yeates, Jérôme Cornil, Jun Takeya, Alessandro Troisi, Henning Sirringhaus, Hall-Effect Measurements Probing the Degree of Charge-Carrier Delocalization in Solution-Processed Crystalline Molecular Semiconductors Physical Review Letters. ,vol. 107, pp. 066601- ,(2011) , 10.1103/PHYSREVLETT.107.066601
Hiromi Minemawari, Toshikazu Yamada, Hiroyuki Matsui, Jun’ya Tsutsumi, Simon Haas, Ryosuke Chiba, Reiji Kumai, Tatsuo Hasegawa, Inkjet printing of single-crystal films Nature. ,vol. 475, pp. 364- 367 ,(2011) , 10.1038/NATURE10313
Aifeng Lv, Sreenivasa R. Puniredd, Jiahui Zhang, Zhibo Li, Hongfei Zhu, Wei Jiang, Huanli Dong, Yudong He, Lang Jiang, Yan Li, Wojciech Pisula, Qing Meng, Wenping Hu, Zhaohui Wang, High Mobility, Air Stable, Organic Single Crystal Transistors of an n-Type Diperylene Bisimide Advanced Materials. ,vol. 24, pp. 2626- 2630 ,(2012) , 10.1002/ADMA.201104987
Xiangfeng Duan, Yu Huang, Charles M. Lieber, Nonvolatile Memory and Programmable Logic from Molecule-Gated Nanowires Nano Letters. ,vol. 2, pp. 487- 490 ,(2002) , 10.1021/NL025532N
J. Takeya, M. Yamagishi, Y. Tominari, R. Hirahara, Y. Nakazawa, T. Nishikawa, T. Kawase, T. Shimoda, S. Ogawa, Very high-mobility organic single-crystal transistors with in-crystal conduction channels Applied Physics Letters. ,vol. 90, pp. 102120- ,(2007) , 10.1063/1.2711393
Yan Zhou, Ting Lei, Lei Wang, Jian Pei, Yong Cao, Jian Wang, High-Performance Organic Field-Effect Transistors from Organic Single-Crystal Microribbons Formed by a Solution Process Advanced Materials. ,vol. 22, pp. 1484- 1487 ,(2010) , 10.1002/ADMA.200904171
Marta Mas-Torrent, Murat Durkut, Peter Hadley, Xavi Ribas, Concepció Rovira, High Mobility of Dithiophene-Tetrathiafulvalene Single-Crystal Organic Field Effect Transistors Journal of the American Chemical Society. ,vol. 126, pp. 984- 985 ,(2004) , 10.1021/JA0393933