Observation of 1.5μm photoluminescence and electroluminescence from a holmium organic complex

作者: FX Zang , WL Li , ZR Hong , HZ Wei , MT Li

DOI: 10.1063/1.1764593

关键词:

摘要: Electroluminescence (EL) and photoluminescence in both the visible near-infrared spectral range were observed from a holmium(dibenzoylmethanato)3(bathophenanthroline) [Ho(DBM)3bath]. Five peaks at 580nm, 660nm, 980nm, 1200nm, 1500nm, respectively, attributed to internal 4f electronical transitions of Ho3+ ions. Except for emissions ions, broadband exciplex emission 480nmto670nm appeared EL cases. The intensity organic interface showed tendency saturation beyond certain driving voltage, while ions kept increasing. This evolution spectra was discussed terms extension charge recombination zone. 1500nm corresponding F55→I65 transition suggests that Ho(DBM)3bath is potential candidate optical communications.

参考文章(18)
Jan W. Stouwdam, Frank C. J. M. van Veggel, Near-infrared Emission of Redispersible Er3+, Nd3+, and Ho3+ Doped LaF3 Nanoparticles Nano Letters. ,vol. 2, pp. 733- 737 ,(2002) , 10.1021/NL025562Q
Shigeki Naka, Hiroyuki Okada, Hiroyoshi Onnagawa, Tetsuo Tsutsui, High electron mobility in bathophenanthroline Applied Physics Letters. ,vol. 76, pp. 197- 199 ,(2000) , 10.1063/1.125701
Yuichiro Kawamura, Yuji Wada, Yasuchika Hasegawa, Mitsunori Iwamuro, Takayuki Kitamura, Shozo Yanagida, Observation of neodymium electroluminescence Applied Physics Letters. ,vol. 74, pp. 3245- 3247 ,(1999) , 10.1063/1.123357
Yong Gyu Choi, Bong Je Park, Kyong Hon Kim, 1.6-micrometer emission from Ho3+-doped fluoride glasses. Optics Letters. ,vol. 28, pp. 622- 624 ,(2003) , 10.1364/OL.28.000622
L. R. Melby, N. J. Rose, E. Abramson, J. C. Caris, Synthesis and Fluorescence of Some Trivalent Lanthanide Complexes Journal of the American Chemical Society. ,vol. 86, pp. 5117- 5125 ,(1964) , 10.1021/JA01077A015
G. A. Crosby, R. E. Whan, R. M. Alire, Intramolecular Energy Transfer in Rare Earth Chelates. Role of the Triplet State The Journal of Chemical Physics. ,vol. 34, pp. 743- 748 ,(1961) , 10.1063/1.1731670
Hiroyuki Suzuki, Infrared electroluminescence from an organic ionic dye containing no rare-earth ions Applied Physics Letters. ,vol. 80, pp. 3256- 3258 ,(2002) , 10.1063/1.1476711
ZR Hong, CJ Liang, RG Li, WL Li, Dan Zhao, Di Fan, DY Wang, Bei Chu, FX Zang, L‐S Hong, S‐T Lee, None, Rare Earth Complex as a High-Efficiency Emitter in an Electroluminescent Device Advanced Materials. ,vol. 13, pp. 1241- 1245 ,(2001) , 10.1002/1521-4095(200108)13:16<1241::AID-ADMA1241>3.0.CO;2-6
Nir Tessler, Vlad Medvedev, Miri Kazes, ShiHai Kan, Uri Banin, Efficient Near-Infrared Polymer Nanocrystal Light-Emitting Diodes Science. ,vol. 295, pp. 1506- 1508 ,(2002) , 10.1126/SCIENCE.1068153
Ziruo Hong, Chunjun Liang, Ruigang Li, Faxin Zang, Di Fan, Wenlian Li, L. S. Hung, S. T. Lee, Infrared and visible emission from organic electroluminescent devices based on praseodymium complex Applied Physics Letters. ,vol. 79, pp. 1942- 1944 ,(2001) , 10.1063/1.1391239