The stability of inclusion compounds under heating
作者： V. Logvinenko , D. Dybtsev , V. Fedin , V. Drebushchak , M. Yutkin
DOI: 10.1007/S10973-009-0444-2
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摘要: The thermal decomposition of two inclusion compounds Mn(HCOO)2·1/3C4H8O2 and Mn(HCOO)2·1/3C4H8O was studied in the inert atmosphere. process both dioxane, tetrahydrofurane removal has steps; intermediate phase is unstable kinetically hindered. Manganese formate stable up to 330°C. Thermogravimetric data (obtained at different rates linear heating) were processed with computer program (with ‘Model free’ approach). Kinetic parameters calculated for first step, described by equation n-order reaction autocatalysis.
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