Crystal structure and thermoanalytical study of a manganese(II) complex with 1-allylimidazole
作者： S. De Angelis Curtis , Krystyna Kurdziel , S. Materazzi , S. Vecchio
DOI: 10.1007/S10973-007-8747-7
关键词: Stereochemistry 、 Crystal structure 、 Physical chemistry 、 Thermogravimetry 、 Coordination complex 、 Evolved gas analysis 、 Manganese 、 Thermal analysis 、 X-ray crystallography 、 Decomposition 、 Chemistry
摘要: The crystal structure of a manganese(II) 1-allylimidazole complex ([Mn(1-AIm)3(NO3)2], where 1-Aim=1-allylimidazole), was characterized by X-ray diffraction (XRD) using SHELX-97. thermal behaviour the investigated thermogravimetry (TG) coupled with an FTIR unit. showed multi-step decomposition related to release ligand molecules, followed oxidation. final residue at 1073 K found be oxide. Evolved gas analysis allowed prove oxidative pattern examined complex, initially proposed percentage mass loss data. Finally, kinetic steps made Kissinger equation, while nature kinetics revealed isoconversional Ozawa-Flynn-Wall method.
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