Vibrational studies of the solid imidazole and pyridine adducts of metal(II) saccharinates. Part II. Mn(II) and Fe(II) imidazole saccharinates
作者： P Naumov , G Jovanovski , A Todorovska
DOI: 10.1016/S0022-2860(00)00937-6
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摘要: Abstract Novel adducts of Mn(II) and Fe(II) saccharinates with imidazole were synthesized their protonated deuterated analogues investigated by the means FT-IR spectroscopy at room liquid-nitrogen boiling temperature. The appearance characteristic OH/OD, NH, CO SO 2 stretching bands was employed together earlier spectra–structure correlations to predict certain structural details about complexes. IR spectra reveal pronounced similarity possible isomorphism Co Ni formula [M(C 3 H 4 N ) (H O) ](C 7 NO S) . There is a single crystallographic type asymmetrically bonded water molecules in structure. All saccharinato ions are structurally equal. O–S–O angles should be similar those Mg(sac) ·7H O Na (sac) ·2H O.
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