Investigation of the terahertz vibrational modes of ZIF-8 and ZIF-90 with terahertz time-domain spectroscopy
作者： Nicholas Y. Tan , Michael T. Ruggiero , Claudia Orellana-Tavra , Tian Tian , Andrew D. Bond
DOI: 10.1039/C5CC06455D
关键词:
摘要: We present experimental and computational evidence that gate-opening modes for zeolitic imidazole frameworks can be observed at terahertz frequencies. Our work highlights the critical importance to correctly optimise crystal structure prior lattice dynamics analysis. The results support hypothesis low energy vibrational do indeed play a significant role in host–guest interactions ZIFs, such as gas loading.
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Juraj Sibik, Michael J. Sargent, Miriam Franklin, J. Axel Zeitler, Crystallization and phase changes in paracetamol from the amorphous solid to the liquid phase. Molecular Pharmaceutics. ,vol. 11, pp. 1326- 1334 ,(2014) , 10.1021/MP400768M
David Fairen-Jimenez, Nigel A. Seaton, Tina Düren, Unusual adsorption behavior on metal-organic frameworks. Langmuir. ,vol. 26, pp. 14694- 14699 ,(2010) , 10.1021/LA102831E
Canan Gücüyener, Johan van den Bergh, Jorge Gascon, Freek Kapteijn, Ethane/Ethene Separation Turned on Its Head: Selective Ethane Adsorption on the Metal−Organic Framework ZIF-7 through a Gate-Opening Mechanism Journal of the American Chemical Society. ,vol. 132, pp. 17704- 17706 ,(2010) , 10.1021/JA1089765
Hai-Long Jiang, Bo Liu, Tomoki Akita, Masatake Haruta, Hiroaki Sakurai, Qiang Xu, Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal−Organic Framework Journal of the American Chemical Society. ,vol. 131, pp. 11302- 11303 ,(2009) , 10.1021/JA9047653
Helge Bux, Fangyi Liang, Yanshuo Li, Janosch Cravillon, Michael Wiebcke, Jürgen Caro, Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis Journal of the American Chemical Society. ,vol. 131, pp. 16000- 16001 ,(2009) , 10.1021/JA907359T
David Fairén-Jiménez, Francisco Carrasco-Marín, David Djurado, Françoise Bley, Françoise Ehrburger-Dolle, Carlos Moreno-Castilla, Surface area and microporosity of carbon aerogels from gas adsorption and small- and wide-angle X-ray scattering measurements. Journal of Physical Chemistry B. ,vol. 110, pp. 8681- 8688 ,(2006) , 10.1021/JP055992F
Roberto Dovesi, Roberto Orlando, Alessandro Erba, Claudio M Zicovich‐Wilson, Bartolomeo Civalleri, Silvia Casassa, Lorenzo Maschio, Matteo Ferrabone, Marco De La Pierre, Philippe D'Arco, Yves Noël, Mauro Causa, Michel Rérat, Bernard Kirtman, None, CRYSTAL14: A program for the ab initio investigation of crystalline solids International Journal of Quantum Chemistry. ,vol. 114, pp. 1287- 1317 ,(2014) , 10.1002/QUA.24658
Juraj Sibik, Evgenyi Y. Shalaev, J. Axel Zeitler, Glassy dynamics of sorbitol solutions at terahertz frequencies Physical Chemistry Chemical Physics. ,vol. 15, pp. 11931- 11942 ,(2013) , 10.1039/C3CP51936H
Matthew R. Ryder, Bartolomeo Civalleri, Thomas D. Bennett, Sebastian Henke, Svemir Rudić, Gianfelice Cinque, Felix Fernandez-Alonso, Jin-Chong Tan, Identifying the Role of Terahertz Vibrations in Metal-Organic Frameworks: From Gate-Opening Phenomenon to Shear-Driven Structural Destabilization Physical Review Letters. ,vol. 113, pp. 215502- 215502 ,(2014) , 10.1103/PHYSREVLETT.113.215502
Anh Phan, Christian J. Doonan, Fernando J. Uribe-Romo, Carolyn B. Knobler, Michael O’Keeffe, Omar M. Yaghi, Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks Accounts of Chemical Research. ,vol. 43, pp. 58- 67 ,(2010) , 10.1021/AR900116G