Synthesis and gas sorption behaviour of ZIF-90 with large pore volume

作者: Paola F. Liguori , Beatrice Russo , Alessandro Melicchio , Giovanni Golemme

DOI: 10.1039/C7NJ03192K

关键词:

摘要: Stoichiometric triethylamine in methanol produces sub-micron ZIF-90 98% yield with the largest gas uptakes ever measured. Micropore volume and surface area are compatible an empty pore network crystallographic data, but occurrence of crystal defects, such as missing ligands or Zn2+ ions, although improbable, can not be ruled out.

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