Hydrogen Carbonate Inhibited and Induced Substitution Reactions of Labile Square‐Planar Diethylenetriaminepalladium(II) Complexes
作者： Ernst Breet , Rudi van Eldik
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摘要: The reaction of labile square-planar diethylenetriaminepalladium(II) complexes with hydrogen carbonate ion was studied by stopped flow spectrophotometry as a function [HCO−3] and [Cl−] constant [Pd], ionic strength temperature to investigate the substitution behaviour nucleophile capable affecting solution pH. kinetic results significantly deviate from those for normal behaviour. comprises two consecutive equilibrations, which have complex kinetics compared simple two-term rate law normally encountered, represent inhibited induced reactions, respectively. suggested mechanism data treatment account observed deviating provide alternative ways obtaining formerly determined aquation anation constants comparable accuracy, even too be monitored directly.
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