First liquid single crystal elastomer containing lactic acid derivative as chiral co-monomer: Synthesis and properties

作者: Alexej Bubnov , Valentina Domenici , Věra Hamplová , Miroslav Kašpar , Bostjan Zalar

DOI: 10.1016/J.POLYMER.2011.07.046

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摘要: Abstract For the first time new type of liquid single crystal elastomers forming chiral smectic A * (SmA ) phase has been prepared using lactic acid derivative as a co-monomer. The synthesis and basic characterization ferroelectric crystalline co-monomer based on differential scanning calorimetry small/wide-angle X-ray scattering are reported discussed. monomer possesses paraelectric SmA SmC phases over broad temperature range. preparation together with their mesomorphic structural properties is also reported. New possess orthogonal 50 K

参考文章(39)
V. Hamplová, A. Bubnov, M. Kas˘par, V. Novotná, M. Glogarová, New series of chiral ferroelectric liquid crystals with the keto group attached to the molecule core Liquid Crystals. ,vol. 30, pp. 492- 497 ,(2003) , 10.1080/0267829031000090869
M. KASPAR, V. HAMPLOVA, S. A. PAKHOMOV, A. M. BUBNOV, F. GUITTARD, H. SVERENYAK, I. STIBOR, P. VANEK, M. GLOGAROVA, New series of ferroelectric liquid crystals with four ester groups Liquid Crystals. ,vol. 24, pp. 599- 605 ,(1998) , 10.1080/026782998207073
Etsushi Nishikawa, Heino Finkelmann, Helmut R. Brand, Smectic A liquid single crystal elastomers showing macroscopic in-plane fluidity Macromolecular Rapid Communications. ,vol. 18, pp. 65- 71 ,(1997) , 10.1002/MARC.1997.030180201
R. Stannarius, R. Köhler, U. Dietrich, M. Lösche, C. Tolksdorf, R. Zentel, Structure and elastic properties of smectic liquid crystalline elastomer films. Physical Review E. ,vol. 65, pp. 041707- 041707 ,(2002) , 10.1103/PHYSREVE.65.041707
Ari Laiho, Panu Hiekkataipale, Janne Ruokolainen, Olli Ikkala, Directing the Smectic Layer Orientation by Shear Flow in Hierarchical Lamellar-within-lamellar Liquid Crystalline Diblock Copolymers Macromolecular Chemistry and Physics. ,vol. 210, pp. 1218- 1223 ,(2009) , 10.1002/MACP.200900102
Christopher M. Spillmann, John H. Konnert, James M. Adams, Jeffrey R. Deschamps, Jawad Naciri, Banahalli R. Ratna, Strain analysis of a chiral smectic-A elastomer. Physical Review E. ,vol. 82, pp. 031705- ,(2010) , 10.1103/PHYSREVE.82.031705
Alexej Bubnov, Vladimíra Novotná, Věra Hamplová, Miroslav Kašpar, Milada Glogarová, Effect of multilactate chiral part of liquid crystalline molecule on mesomorphic behaviour Journal of Molecular Structure. ,vol. 892, pp. 151- 157 ,(2008) , 10.1016/J.MOLSTRUC.2008.05.016
Alexej Bubnov, Vladimíra Novotná, Damian Pociecha, Miroslav Kašpar, Vĕra Hamplová, Giancarlo Galli, Milada Glogarová, A Liquid-Crystalline Co-Polysiloxane with Asymmetric Bent Side Chains Macromolecular Chemistry and Physics. ,vol. 212, pp. 191- 197 ,(2011) , 10.1002/MACP.201000356
Mitchell Anthamatten, Wen Yue Zheng, Paula T. Hammond, A Morphological Study of Well-Defined Smectic Side-Chain LC Block Copolymers Macromolecules. ,vol. 32, pp. 4838- 4848 ,(1999) , 10.1021/MA9903153
Christopher M Spillmann, Banahalli R Ratna, Jawad Naciri, None, Anisotropic actuation in electroclinic liquid crystal elastomers Applied Physics Letters. ,vol. 90, pp. 021911- ,(2007) , 10.1063/1.2420780