Method for converting lignocellulosic biomasses into mono- or poly-oxygenated molecules

作者: Emmanuelle Guillon , Amandine Cabiac , Damien Delcroix , Christophe Vallee

DOI:

关键词:

摘要: The invention relates to a method for converting lignocellulosic biomass or cellulose into mono- poly-oxygenated compounds, in which the is placed contact simultaneously with catalytic system including combination of one more homogeneous catalysts and heterogeneous catalysts, single reaction chamber, presence at least solvent, said solvent being only water mixed other reducing atmosphere, temperature 80 °C 250 pressure 0.5 MPa 20 MPa.

参考文章(9)
Tom N. Kalnes, John Q. Chen, Joseph A. Kocal, Process for generation of polyols from saccharides ,(2011)
Hongping Yie, Meg M. Sun, Zuolin Zhu, Process of producing liquid fuel from cellulosic biomass ,(2009)
Jacobus Cornelis Rasser, Armand Eduard Rosheuvel, Paul O'connor, Jacob Adriaan Moulijn, Michiel Makkee, Jianrong Li, Simultaneous hydrolysis and hydrogenation of cellulose ,(2011)
Jianrong Li, Helena S. M. P. Soares, Jacob A. Moulijn, Michiel Makkee, Simultaneous hydrolysis and hydrogenation of cellobiose to sorbitol in molten salt hydrate media Catalysis Science & Technology. ,vol. 3, pp. 1565- 1572 ,(2013) , 10.1039/C3CY20808G
Nicholas P. Vasilakos, Marcio T. Barreiros, Homogeneous catalytic hydrogenolysis of biomass Industrial & Engineering Chemistry Process Design and Development. ,vol. 23, pp. 755- 763 ,(1984) , 10.1021/I200027A022
Zhijun Tai, Junying Zhang, Aiqin Wang, Mingyuan Zheng, Tao Zhang, Temperature-controlled phase-transfer catalysis for ethylene glycol production from cellulose. Chemical Communications. ,vol. 48, pp. 7052- 7054 ,(2012) , 10.1039/C2CC32305B
Jingguang Chen, Mingyuan Zheng, Tao Zhang, Aigin Wang, Yuying Shu, Xiaodong Wang, Hui Wang, Na Ji, Method of preparing ethylene glycol from cellulose ,(2008)
D. R. Lide, Handbook of Chemistry and Physics CRC PRESS. ,(1992)