Spectroscopic characterization of humic-like substances in airborne particulate matter
作者： N. Havers , P. Burba , J. Lambert , D. Klockow
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摘要: In a standard reference air dust (NIST 1648 – urban particulate matter) as well in airborne matter collected German and rural areas (Dortmund, Sauerland) 10% more of the organic carbon can be attributed to macromolecular substances like humic fulvic acids (HA, FA). Indirect evidence for presence humin was also obtained. HA FA extracted from NIST other atmospheric particles using 0.1 m NaOH isolated by ion-exchangers were characterized their molecular-size distribution applying multistage ultrafiltration, content UV/VIS, Fourier-transformed infrared (FTIR) nuclear magnetic resonance (1H-NMR) spectra. Summarizing, structural studies exhibit that these humic-like (HULIS) contained samples are small molecular size rich aliphatic carbohydrate substructures compared soils aquatic systems.
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Veli-Matti Kerminen, Timo E. Mäkelä, Christina H. Ojanen, Risto E. Hillamo, Juha K. Vilhunen, Leena Rantanen, Nicole Havers, Alex von Bohlen, Dieter Klockow, Characterization of the Particulate Phase in the Exhaust from a Diesel Car Environmental Science & Technology. ,vol. 31, pp. 1883- 1889 ,(1997) , 10.1021/ES960520N
Lynn M. Hildemann, Wolfgang F. Rogge, Glen R. Cass, Monica A. Mazurek, Bernd R. T. Simoneit, Contribution of primary aerosol emissions from vegetation‐derived sources to fine particle concentrations in Los Angeles Journal of Geophysical Research. ,vol. 101, pp. 19541- 19549 ,(1996) , 10.1029/95JD02136
R. Cini, N. Degliinnocenti, G. Loglio, C. Oppo, G. Orlandi, A. M. Stortini, U. Tesei, R. Udisti, Air-Sea Exchange: Sea Salt and Organic Microcomponents in Antarctic Snow International Journal of Environmental Analytical Chemistry. ,vol. 63, pp. 15- 27 ,(1996) , 10.1080/03067319608039806
Bernd R.T. Simoneit, Eolian particulates from oceanic and rural areas—their lipids fulvic and humic acids and residual carbon Physics and Chemistry of The Earth. ,vol. 12, pp. 343- 352 ,(1980) , 10.1016/0079-1946(79)90117-4
Peter Burba, Valerij Shkinev, Boris Ya. Spivakov, On-line fractionation and characterization of aquatic humic substances by means of sequential-stage ultrafiltration Fresenius Journal of Analytical Chemistry. ,vol. 351, pp. 74- 82 ,(1995) , 10.1007/BF00324294
M. Kunit, H. Puxbaum, Enzymatic determination of the cellulose content of atmospheric aerosols Atmospheric Environment. ,vol. 30, pp. 1233- 1236 ,(1996) , 10.1016/1352-2310(95)00429-7
Hitoshi Mukai, Yoshinari Ambe, Characterization of a humic acid-like brown substance in airborne particulate matter and tentative identification of its origin Atmospheric Environment (1967). ,vol. 20, pp. 813- 819 ,(1986) , 10.1016/0004-6981(86)90265-9
Wolfgang F. Rogge, Monica A. Mazurek, Lynn M. Hildemann, Glen R. Cass, Bernd R.T. Simoneit, Quantification of urban organic aerosols at a molecular level: Identification, abundance and seasonal variation Atmospheric Environment. Part A. General Topics. ,vol. 27, pp. 1309- 1330 ,(1993) , 10.1016/0960-1686(93)90257-Y
SV Khan, M Shcnitzer, None, Soil Organic Matter. Elsevier Scientific Pub. Co.. ,(1978)
Ronald L. Malcolm, Factors to be considered in the isolation and characterization of aquatic humic substances Lecture Notes in Earth Sciences, Berlin Springer Verlag. ,vol. 33, pp. 7- 36 ,(1991) , 10.1007/BFB0010455